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- W2807362216 abstract "Abstract Organocatalytic polymerization reactions have a number of advantages over their metal-catalyzed counterparts, including environmental friendliness, ease of catalyst synthesis and storage, and alternative reaction pathways. Here we introduce an organocatalytic polymerization method called benzylic chloromethyl-coupling polymerization (BCCP). BCCP is catalyzed by organocatalysts not previously employed in polymerization processes (sulfenate anions), which are generated from bench-stable sulfoxide precatalysts. The sulfenate anion promotes an umpolung polycondensation via step-growth propagation cycles involving sulfoxide intermediates. BCCP represents an example of an organocatalyst that links monomers by C=C double bond formation and offers transition metal-free access to a wide variety of polymers that cannot be synthesized by traditional precursor routes." @default.
- W2807362216 created "2018-06-13" @default.
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- W2807362216 date "2018-05-01" @default.
- W2807362216 modified "2023-10-12" @default.
- W2807362216 title "Sulfenate anions as organocatalysts for benzylic chloromethyl coupling polymerization via C=C bond formation" @default.
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- W2807362216 doi "https://doi.org/10.1038/s41467-018-04095-x" @default.
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