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- W2807418200 abstract "Carbon nitride is emerging as leading candidate for photocatalyst which enables one to use light to drive hydrogen production reactions. However, noble-metal such as Pt was adopted to be effective co-catalyst to increase the activity of g-C3N4 in most reactions which is costly. Herein, a novel g-C3N4-based photocatalyst with NiSe2 and CoSe2 as cocatalysts (abbreviated as CN-CoNiSe) in absence of noble-metal applied in photocatalytic hydrogen production was devised with a lamellar structure through a calcination process of the mixture of Ni2+ doped ZIF-67 and g-C3N4 for the first time in this work. The optimum photocatalytic activity in hydrogen evolution for CN-CoNiSe photocatalysts with a Ni2+ doped ZIF-67 mass content in precursors of 5 wt% (854.1 μmol g−1 h−1) was up to 87.4 times as high as that of pure g-C3N4 (9.77 μmol g−1 h−1). The greatly improved photocatalytic activity of CN-CoNiSe photocatalysts was mainly attributed to the synergistic effect of NiSe2, CoSe2 and g-C3N4, which leads to enhanced charge transfer and separation rate based on the results of electrochemical experiments and photoluminescence." @default.
- W2807418200 created "2018-06-13" @default.
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- W2807418200 date "2018-10-01" @default.
- W2807418200 modified "2023-10-10" @default.
- W2807418200 title "Improvement of the photocatalytic hydrogen production activity of g-C3N4 by doping selenides as cocatalysts" @default.
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- W2807418200 doi "https://doi.org/10.1016/j.mssp.2018.05.024" @default.
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