FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2807472246> ?p ?o ?g. }

• W2807472246 abstract "Abstract Amino acids are emerging as alternative solvents for absorption-based CO2 capture, but their potential to form the harmful byproducts nitrosamines is not well understood. This study investigated the formation of nitrosamines from model amino acids sarcosine, proline, and taurine under desorber- and absorber-relevant conditions. Special attention was paid to the effects of base and the formation of volatile nitrosamines. Under simulated desorber conditions, all three amino acid solvents with organic base monoethanolamine (MEA) formed more total nitrosamines than those with inorganic base sodium hydroxide (NaOH). Increasing base concentration decreased the formation of N-nitrososarcosine (NSAR) in both NaOH- and MEA-based sarcosine solvents. By measuring NSAR formation under varying base concentration and CO2 loading, it was shown that both sarcosine carbamic acid (SARCOOH) and deprotonated sarcosine (SAR−) contributed to NSAR formation. Volatile nitrosamine N-nitrosodimethylamine (NDMA) was detected in sarcosine solvents at levels three orders of magnitude lower than NSAR. Kinetic modeling showed that 61%–110% of the accumulated NDMA was formed through NSAR decomposition. NDMA formation from NSAR was promoted by increasing MEA concentration, but suppressed by increasing NaOH concentration. Under simulated absorber conditions, NaOH- and MEA-based solvents formed total nitrosamines at similar rates for sarcosine, proline, and taurine. In sarcosine solvents, NDMA formed at levels three orders of magnitude lower than NSAR, similar to that under desorber conditions." @default.
• W2807472246 created "2018-06-13" @default.
• W2807472246 creator A5002992798 @default.
• W2807472246 creator A5024780351 @default.
• W2807472246 creator A5082396407 @default.
• W2807472246 date "2018-08-01" @default.
• W2807472246 modified "2023-09-24" @default.
• W2807472246 title "Kinetics and pathways for nitrosamine formation in amino acid-based carbon dioxide capture systems" @default.
• W2807472246 cites W1965678206 @default.
• W2807472246 cites W1972467736 @default.
• W2807472246 cites W1974789605 @default.
• W2807472246 cites W1981157671 @default.
• W2807472246 cites W1987940097 @default.
• W2807472246 cites W1997171443 @default.
• W2807472246 cites W2013951339 @default.
• W2807472246 cites W2018878626 @default.
• W2807472246 cites W2028497967 @default.
• W2807472246 cites W2032797438 @default.
• W2807472246 cites W2039841086 @default.
• W2807472246 cites W2044373144 @default.
• W2807472246 cites W2050292163 @default.
• W2807472246 cites W2052858466 @default.
• W2807472246 cites W2061995385 @default.
• W2807472246 cites W2062396111 @default.
• W2807472246 cites W2063570106 @default.
• W2807472246 cites W2069925783 @default.
• W2807472246 cites W2079589636 @default.
• W2807472246 cites W2079875644 @default.
• W2807472246 cites W2080480429 @default.
• W2807472246 cites W2091819966 @default.
• W2807472246 cites W2115330167 @default.
• W2807472246 cites W2126477949 @default.
• W2807472246 cites W2129804024 @default.
• W2807472246 cites W2150390047 @default.
• W2807472246 cites W2259402094 @default.
• W2807472246 cites W2288921689 @default.
• W2807472246 cites W2319266827 @default.
• W2807472246 cites W2323013313 @default.
• W2807472246 cites W2326532151 @default.
• W2807472246 cites W2326639051 @default.
• W2807472246 cites W2334130150 @default.
• W2807472246 cites W2559116413 @default.
• W2807472246 cites W2586478297 @default.
• W2807472246 cites W2586823725 @default.
• W2807472246 cites W2757780399 @default.
• W2807472246 cites W4245571674 @default.
• W2807472246 doi "https://doi.org/10.1016/j.ijggc.2018.04.019" @default.
• W2807472246 hasPublicationYear "2018" @default.
• W2807472246 type Work @default.
• W2807472246 sameAs 2807472246 @default.
• W2807472246 citedByCount "0" @default.
• W2807472246 crossrefType "journal-article" @default.
• W2807472246 hasAuthorship W2807472246A5002992798 @default.
• W2807472246 hasAuthorship W2807472246A5024780351 @default.
• W2807472246 hasAuthorship W2807472246A5082396407 @default.
• W2807472246 hasConcept C114246631 @default.
• W2807472246 hasConcept C134306372 @default.
• W2807472246 hasConcept C150394285 @default.
• W2807472246 hasConcept C162711632 @default.
• W2807472246 hasConcept C178790620 @default.
• W2807472246 hasConcept C179104552 @default.
• W2807472246 hasConcept C185592680 @default.
• W2807472246 hasConcept C2777395278 @default.
• W2807472246 hasConcept C2777756961 @default.
• W2807472246 hasConcept C2779943223 @default.
• W2807472246 hasConcept C33923547 @default.
• W2807472246 hasConcept C42058472 @default.
• W2807472246 hasConcept C515207424 @default.
• W2807472246 hasConcept C55493867 @default.
• W2807472246 hasConceptScore W2807472246C114246631 @default.
• W2807472246 hasConceptScore W2807472246C134306372 @default.
• W2807472246 hasConceptScore W2807472246C150394285 @default.
• W2807472246 hasConceptScore W2807472246C162711632 @default.
• W2807472246 hasConceptScore W2807472246C178790620 @default.
• W2807472246 hasConceptScore W2807472246C179104552 @default.
• W2807472246 hasConceptScore W2807472246C185592680 @default.
• W2807472246 hasConceptScore W2807472246C2777395278 @default.
• W2807472246 hasConceptScore W2807472246C2777756961 @default.
• W2807472246 hasConceptScore W2807472246C2779943223 @default.
• W2807472246 hasConceptScore W2807472246C33923547 @default.
• W2807472246 hasConceptScore W2807472246C42058472 @default.
• W2807472246 hasConceptScore W2807472246C515207424 @default.
• W2807472246 hasConceptScore W2807472246C55493867 @default.
• W2807472246 hasFunder F4320306076 @default.
• W2807472246 hasFunder F4320332641 @default.
• W2807472246 hasLocation W28074722461 @default.
• W2807472246 hasOpenAccess W2807472246 @default.
• W2807472246 hasPrimaryLocation W28074722461 @default.
• W2807472246 hasRelatedWork W1995170976 @default.
• W2807472246 hasRelatedWork W2034591574 @default.
• W2807472246 hasRelatedWork W2062273021 @default.
• W2807472246 hasRelatedWork W2559647089 @default.
• W2807472246 hasRelatedWork W2949318170 @default.
• W2807472246 hasRelatedWork W2949479003 @default.
• W2807472246 hasRelatedWork W2950703150 @default.
• W2807472246 hasRelatedWork W2951675011 @default.
• W2807472246 hasRelatedWork W2952198646 @default.
• W2807472246 hasRelatedWork W2953268811 @default.
• W2807472246 isParatext "false" @default.
• W2807472246 isRetracted "false" @default.

• next