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• W2807557724 abstract "A new bulky silazido ligand, -N(SiHMe2)Dipp (Dipp = C6H3-2,6-iPr2), supports planar, three-coordinate homoleptic rare earth complexes Ln{N(SiHMe2)Dipp}3 (Ln = Sc, Y, and Lu), each containing three secondary Ln↼HSi interactions and one agostic CH bond. Y{N(SiHMe2)Dipp}3 and acetophenone react via hydrosilylation, rather than by insertion into the Y-N bond or by enolate formation." @default.
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• W2807557724 date "2018-01-01" @default.
• W2807557724 modified "2023-10-18" @default.
• W2807557724 title "Rare earth arylsilazido compounds with inequivalent secondary interactions" @default.
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• W2807557724 doi "https://doi.org/10.1039/c8cc03186j" @default.
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