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• W2807644567 startingPage "979" @default.
• W2807644567 abstract "A vitamin B12 derivative with a trifluoromethyl group as an axial ligand, heptamethyl trifluoromethylaquacobyrinate perchlorate, [[(CF3)(H2O)Cob(III)7C1ester]ClO4], is prepared and characterized by elemental analysis, 1H NMR, 19F NMR, ESI-MS, UV-vis absorption, and cyclic voltammetry. The Co–CF3 complex shows homolysis of the Co(III)–CF3 bond under visible light irradiation, which releases a CF3 radical that can be detected by a radical trapping experiment. A vitamin B12 derivative with a trifluoromethyl group as axial ligand, heptamethyl trifluoromethylaquacobyrinate perchlorate, [[(CF3)(H2O)Cob(III)7C1ester]ClO4], is prepared and characterized by elemental analysis, 1H NMR, 19F NMR, UV-vis absorption, ESI-MS, and cyclic voltammetry. The Co–perfluoroalkyl complex shows homolysis of the Co(III)–CF3 bond under visible light irradiation, which releases a CF3 radical that can be detected by radical trapping experiment." @default.
• W2807644567 created "2018-06-13" @default.
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• W2807644567 date "2018-08-05" @default.
• W2807644567 modified "2023-10-16" @default.
• W2807644567 title "Synthesis of Trifluoromethylated B₁₂ Derivative and Photolysis of Cobalt(III)–Trifluoromethyl Bond" @default.
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• W2807644567 doi "https://doi.org/10.1246/cl.180355" @default.
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