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- W2807775903 abstract "Abstract The solvothermal reaction of (HL = 2-(5-Pyrazinyl-1H-[1,2,4]triazol-3-yl)-pyrazine) and NiCl2·6H2O and Mn(HCOO)2·2H2O yielded two novel complexes, namely, Ni(L)(Cl)(DMF) (HPU-11) and {Mn(L)(HCOO)}n (HPU-12), which have been studied based on X-ray single crystal diffraction analysis. In HPU-11, two crystallographic independent NiII ions are connected by two L− ligands to generate a centrosymmetric binuclear cluster. By changing the terminal coordination atom Cl as HCOO, chiral magnet HPU-12 was obtained. In HPU-12, adjacent Mn ions are connected by HCOO− bridges giving rise to a one-dimensional chiral chain structure. The magnetic measurements show the presence of antiferromagnetic interactions between the magnetic centers of the two complexes." @default.
- W2807775903 created "2018-06-21" @default.
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- W2807775903 date "2018-11-01" @default.
- W2807775903 modified "2023-09-27" @default.
- W2807775903 title "Synthesis and magnetic properties of chiral molecular magnet regulated by terminal coordination groups" @default.
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- W2807775903 doi "https://doi.org/10.1016/j.poly.2018.06.007" @default.
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