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• W2808056064 endingPage "11563" @default.
• W2808056064 startingPage "11559" @default.
• W2808056064 abstract "Abstract Trifluoromethyl‐containing compounds play a significant role in medicinal chemistry, materials and fine chemistry. Although direct C−H trifluoromethylation has been achieved on Csp 2 −H bonds, direct conversion of Csp 3 −H bonds to Csp 3 −CF 3 remains challenging. We report herein an efficient protocol for the selective trifluoromethylation of benzylic C−H bonds. This process is mediated by a combination Cu III −CF 3 species and persulfate salts. A wide range of methylarenes can be selectively trifluoromethylated at the benzylic positions. A combination of experimental and theoretical mechanistic studies suggests that the reaction involves a radical intermediate and a Cu III −CF 3 species as the CF 3 transfer reagent." @default.
• W2808056064 created "2018-06-21" @default.
• W2808056064 creator A5003228926 @default.
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• W2808056064 creator A5065451219 @default.
• W2808056064 creator A5082527912 @default.
• W2808056064 creator A5090161094 @default.
• W2808056064 date "2018-07-18" @default.
• W2808056064 modified "2023-10-18" @default.
• W2808056064 title "Copper‐Mediated Trifluoromethylation of Benzylic Csp³−H Bonds" @default.
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