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- W2808445406 abstract "Sulfide-modified nanoscale zerovalent iron (S-nZVI) was effectively utilized for the reduction of various contaminants, despite its applicability being limited due to agglomeration, oxidation and electron loss. In this study, biochar (BC)-supported S-nZVI was prepared to enhance the reactivity of S-nZVI for nitrobenzene (NB) reduction. Scanning electron microscopy images showed that the S-nZVI particles were well-dispersed on the BC surface as well as in the channels. NB removal and aniline formation could be significantly enhanced by using S-nZVI@BC, as compared to S-nZVI and blank BC. NB removal by S-nZVI@BC followed the pseudo second-order kinetics model and Langmuir isotherm model, suggesting hybrid chemical reaction-sorption was involved. Furthermore, a possible reaction mechanism for enhanced NB removal by S-nZVI@BC was proposed, including chemical adsorption of NB onto S-nZVI@BC, direct reduction by S-nZVI and enhanced electron transfer. The high reducibility of S-nZVI@BC as well as its excellent antioxidation ability and reusability demonstrated its promising prospects in remediation applications." @default.
- W2808445406 created "2018-06-21" @default.
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- W2808445406 date "2018-01-01" @default.
- W2808445406 modified "2023-10-16" @default.
- W2808445406 title "Biochar supported sulfide-modified nanoscale zero-valent iron for the reduction of nitrobenzene" @default.
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- W2808445406 doi "https://doi.org/10.1039/c8ra04314k" @default.
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