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• W2808543399 abstract "A new bidentate directing group, 3-amino-1-methyl-1H-pyridin-2-one, is introduced to achieve a powerful PdII metallacycle for selective γ-C(sp3)–H activation and arylation of aromatic and aliphatic carboxylic acid derivatives. The versatility of the directing group is validated for remote arylation of β-C(sp3)–H, β-C(sp2)–H, and γ-C(sp2)–H to achieve therapeutically important 2-pyridone analogues and arylated acid synthons. The traceless removal of the directing group to retrieve the directing element and carboxylic acids makes this method more interesting." @default.
• W2808543399 created "2018-06-21" @default.
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• W2808543399 date "2018-06-12" @default.
• W2808543399 modified "2023-10-14" @default.
• W2808543399 title "3-Amino-1-methyl-1<i>H</i>-pyridin-2-one-Directed Pd^II Catalysis: C(sp³)–H Activated Diverse Arylation Reaction" @default.
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• W2808543399 doi "https://doi.org/10.1021/acs.orglett.8b01618" @default.
• W2808543399 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29894193" @default.
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