Matches in SemOpenAlex for { <https://semopenalex.org/work/W2808733163> ?p ?o ?g. }
- W2808733163 endingPage "4946" @default.
- W2808733163 startingPage "4934" @default.
- W2808733163 abstract "Abstract The hydrolysis of cellulose and hemicelluloses in the presence of solid acid catalysts is of great importance as an entry process for the production of biofuels and chemicals. In this work, the effect of carbon surface chemistry on the catalyst conversion and selectivity in hydrolysis of cellobiose to glucose was studied. Solid catalysts based on carbon xerogels (CXs) containing various functionalities incorporating heteroatoms (S, P, N, O), as confirmed by XPS, TPD, ICP and EA analyses, were successfully prepared. CXs containing 3.4 wt % of phosphorus showed the best catalytic performance, reaching 90 % conversion of cellobiose with 72 % selectivity to glucose, under oxidative atmosphere and in a short reaction time of only 4 h. The presence of phosphonates (−P−C−) was found to increase the selectivity to glucose up to unprecedented 87 %. On the contrary, carbonyls, quinones, pyrydinic, pyrrolic and sulfonic groups were found to promote glucose degradation, leading to a final low yield of this product. Additionally, the increased concentration of oxygen in the reaction atmosphere was shown to significantly weaken the β (1–4)‐glycosidic bond, increasing the final yield of glucose." @default.
- W2808733163 created "2018-06-29" @default.
- W2808733163 creator A5033400067 @default.
- W2808733163 creator A5035523109 @default.
- W2808733163 creator A5064620990 @default.
- W2808733163 creator A5089258889 @default.
- W2808733163 date "2018-10-30" @default.
- W2808733163 modified "2023-10-16" @default.
- W2808733163 title "Cutting the Green Waste. Structure‐Performance Relationship in Functionalized Carbon Xerogels for Hydrolysis of Cellobiose" @default.
- W2808733163 cites W1255648802 @default.
- W2808733163 cites W1971752637 @default.
- W2808733163 cites W1973250570 @default.
- W2808733163 cites W1976708215 @default.
- W2808733163 cites W1980265514 @default.
- W2808733163 cites W1981657612 @default.
- W2808733163 cites W1984392653 @default.
- W2808733163 cites W1989998796 @default.
- W2808733163 cites W1994910521 @default.
- W2808733163 cites W1997722813 @default.
- W2808733163 cites W1998321859 @default.
- W2808733163 cites W1999657313 @default.
- W2808733163 cites W2005915372 @default.
- W2808733163 cites W2007525992 @default.
- W2808733163 cites W2008901768 @default.
- W2808733163 cites W2010088751 @default.
- W2808733163 cites W2012348150 @default.
- W2808733163 cites W2025235302 @default.
- W2808733163 cites W2036683485 @default.
- W2808733163 cites W2043485463 @default.
- W2808733163 cites W2045082158 @default.
- W2808733163 cites W2046066141 @default.
- W2808733163 cites W2048657438 @default.
- W2808733163 cites W2049686632 @default.
- W2808733163 cites W2054713863 @default.
- W2808733163 cites W2064542338 @default.
- W2808733163 cites W2065232399 @default.
- W2808733163 cites W2070582127 @default.
- W2808733163 cites W2072727165 @default.
- W2808733163 cites W2080962199 @default.
- W2808733163 cites W2081939820 @default.
- W2808733163 cites W2085028585 @default.
- W2808733163 cites W2085176115 @default.
- W2808733163 cites W2088558213 @default.
- W2808733163 cites W2094215650 @default.
- W2808733163 cites W2094909582 @default.
- W2808733163 cites W2112520292 @default.
- W2808733163 cites W2112947303 @default.
- W2808733163 cites W2113270067 @default.
- W2808733163 cites W2113690951 @default.
- W2808733163 cites W2122865264 @default.
- W2808733163 cites W2123457457 @default.
- W2808733163 cites W2139295479 @default.
- W2808733163 cites W2152123339 @default.
- W2808733163 cites W2164117905 @default.
- W2808733163 cites W2165580199 @default.
- W2808733163 cites W2184806743 @default.
- W2808733163 cites W2196076729 @default.
- W2808733163 cites W2205963256 @default.
- W2808733163 cites W2282537201 @default.
- W2808733163 cites W2300496908 @default.
- W2808733163 cites W2323621643 @default.
- W2808733163 cites W2426647429 @default.
- W2808733163 cites W2432885532 @default.
- W2808733163 cites W2509836018 @default.
- W2808733163 cites W2526272818 @default.
- W2808733163 cites W2539955681 @default.
- W2808733163 cites W2580321522 @default.
- W2808733163 cites W2606089421 @default.
- W2808733163 cites W2606974208 @default.
- W2808733163 cites W2793632868 @default.
- W2808733163 cites W4234976046 @default.
- W2808733163 doi "https://doi.org/10.1002/cctc.201800649" @default.
- W2808733163 hasPublicationYear "2018" @default.
- W2808733163 type Work @default.
- W2808733163 sameAs 2808733163 @default.
- W2808733163 citedByCount "9" @default.
- W2808733163 countsByYear W28087331632020 @default.
- W2808733163 countsByYear W28087331632021 @default.
- W2808733163 countsByYear W28087331632022 @default.
- W2808733163 countsByYear W28087331632023 @default.
- W2808733163 crossrefType "journal-article" @default.
- W2808733163 hasAuthorship W2808733163A5033400067 @default.
- W2808733163 hasAuthorship W2808733163A5035523109 @default.
- W2808733163 hasAuthorship W2808733163A5064620990 @default.
- W2808733163 hasAuthorship W2808733163A5089258889 @default.
- W2808733163 hasConcept C104779481 @default.
- W2808733163 hasConcept C118792377 @default.
- W2808733163 hasConcept C134121241 @default.
- W2808733163 hasConcept C140205800 @default.
- W2808733163 hasConcept C141603559 @default.
- W2808733163 hasConcept C159985019 @default.
- W2808733163 hasConcept C161790260 @default.
- W2808733163 hasConcept C178790620 @default.
- W2808733163 hasConcept C185592680 @default.
- W2808733163 hasConcept C191897082 @default.
- W2808733163 hasConcept C192562407 @default.
- W2808733163 hasConcept C20950531 @default.
- W2808733163 hasConcept C2779251873 @default.