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- W2808902017 abstract "Abstract A microporous metal–organic framework (MOF), [Cd(IP)Cl]n (1, HIP = 1H-imidazo[4,5-f][1,10]phenanthroline), with 1D square channels along the c axis was constructed through the solvothermal method. Because of the polar nitrogen atoms and the π-electron-rich ligand, activated MOF 1a presents a strong interaction with CO2, showing selective capture of CO2 from a mixture of CO2/N2. Additionally, MOF 1a also shows significant selective capture of CO2 from CO2/CH4 and CO2/C2H4 mixtures due to the sieving effect of the 1D channels. The column breakthrough experiment results further confirmed that microporous MOF 1a could be used as a potential porous material for selective CO2 adsorption." @default.
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- W2808902017 date "2018-09-01" @default.
- W2808902017 modified "2023-10-08" @default.
- W2808902017 title "Synthesis, crystal structure and adsorption property of a microporous Cd(II) metal–organic framework based on 1H-imidazo[4,5-f][1,10]phenanthroline" @default.
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- W2808902017 doi "https://doi.org/10.1016/j.poly.2018.06.025" @default.
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