Matches in SemOpenAlex for { <https://semopenalex.org/work/W2808932433> ?p ?o ?g. }
- W2808932433 endingPage "203" @default.
- W2808932433 startingPage "192" @default.
- W2808932433 abstract "Abstract Catalytic destruction of nitrogen-containing volatile organic compounds (NVOCs) is rarely reported although they can make great harm to the environment and public health. In the present work, a series of short rod-like micro-mesoporous composite SBA-15 materials (SBA-15-r) with developed porosity and enhanced mass transfer performance were rationally designed and synthesized, and highly dispersed and thermally stable Pd nanoparticles were successfully introduced into the mesopore channels of SBA-15-r via an extraordinary incipient wetness impregnation with the assistance of furfuryl alcohol and trimethylbenzene. The correlation between catalyst property and catalytic performance in n-butylamine destruction was elucidated. 29Si MAS NMR and FT-IR results show that phosphorus is incorporated into the skeleton of SBA-15-r through a P O Si connection, altering the structural property of support. All Pd/SBA-15-r materials are highly active and stable catalysts with n-butylamine totally converted at 280 °C. Amongst, Pd/S-5 possesses the best n-butylamine oxidation activity and lowest NOx formation rate ascribable to the largest surface area and highest porosity which can promote the dispersion of Pd active sites and accelerate the oxidation process and product diffusion, inhibiting the formation of reaction byproducts. Moreover, the structural micropores over Pd/SBA-15-r catalysts play an important positive role in NOx formation control. The n-butylamine destruction mechanism were further discussed according to the results of gas chromatography and in situ DRIFTS. We believe that the present work provides new insights into the design and application of high-efficient catalysts based on hierarchical materials in NVOC elimination." @default.
- W2808932433 created "2018-06-29" @default.
- W2808932433 creator A5007188554 @default.
- W2808932433 creator A5014844829 @default.
- W2808932433 creator A5015017986 @default.
- W2808932433 creator A5035684336 @default.
- W2808932433 creator A5040508866 @default.
- W2808932433 creator A5060946821 @default.
- W2808932433 creator A5071221488 @default.
- W2808932433 date "2018-08-01" @default.
- W2808932433 modified "2023-10-14" @default.
- W2808932433 title "Highly active SBA-15-confined Pd catalyst with short rod-like micro-mesoporous hybrid nanostructure for n-butylamine low-temperature destruction" @default.
- W2808932433 cites W1964594150 @default.
- W2808932433 cites W1965331908 @default.
- W2808932433 cites W1966927530 @default.
- W2808932433 cites W1968449445 @default.
- W2808932433 cites W1971285654 @default.
- W2808932433 cites W1979497907 @default.
- W2808932433 cites W1988745485 @default.
- W2808932433 cites W1991324483 @default.
- W2808932433 cites W1993628166 @default.
- W2808932433 cites W1996185557 @default.
- W2808932433 cites W1998552345 @default.
- W2808932433 cites W1998592181 @default.
- W2808932433 cites W2002917210 @default.
- W2808932433 cites W2004421274 @default.
- W2808932433 cites W2013100151 @default.
- W2808932433 cites W2015043204 @default.
- W2808932433 cites W2016177915 @default.
- W2808932433 cites W2016817309 @default.
- W2808932433 cites W2016898890 @default.
- W2808932433 cites W2017820453 @default.
- W2808932433 cites W2023143493 @default.
- W2808932433 cites W2038001963 @default.
- W2808932433 cites W2043641117 @default.
- W2808932433 cites W2048537250 @default.
- W2808932433 cites W2051185682 @default.
- W2808932433 cites W2056461200 @default.
- W2808932433 cites W2058053005 @default.
- W2808932433 cites W2059109048 @default.
- W2808932433 cites W2060230829 @default.
- W2808932433 cites W2065271020 @default.
- W2808932433 cites W2068780073 @default.
- W2808932433 cites W2070195987 @default.
- W2808932433 cites W2078523014 @default.
- W2808932433 cites W2078677165 @default.
- W2808932433 cites W2079170982 @default.
- W2808932433 cites W2079342781 @default.
- W2808932433 cites W2093912621 @default.
- W2808932433 cites W2103233783 @default.
- W2808932433 cites W2120623915 @default.
- W2808932433 cites W2146795650 @default.
- W2808932433 cites W2325535163 @default.
- W2808932433 cites W2330012213 @default.
- W2808932433 cites W2331175576 @default.
- W2808932433 cites W2331662606 @default.
- W2808932433 cites W2338966395 @default.
- W2808932433 cites W2341466078 @default.
- W2808932433 cites W2509047800 @default.
- W2808932433 cites W2519009577 @default.
- W2808932433 cites W2607300815 @default.
- W2808932433 cites W2609330105 @default.
- W2808932433 cites W2615331809 @default.
- W2808932433 cites W2766436521 @default.
- W2808932433 cites W2772317413 @default.
- W2808932433 cites W2774455954 @default.
- W2808932433 cites W2781618669 @default.
- W2808932433 cites W2781887899 @default.
- W2808932433 cites W2782467321 @default.
- W2808932433 doi "https://doi.org/10.1016/j.mcat.2018.06.016" @default.
- W2808932433 hasPublicationYear "2018" @default.
- W2808932433 type Work @default.
- W2808932433 sameAs 2808932433 @default.
- W2808932433 citedByCount "41" @default.
- W2808932433 countsByYear W28089324332018 @default.
- W2808932433 countsByYear W28089324332019 @default.
- W2808932433 countsByYear W28089324332020 @default.
- W2808932433 countsByYear W28089324332021 @default.
- W2808932433 countsByYear W28089324332022 @default.
- W2808932433 countsByYear W28089324332023 @default.
- W2808932433 crossrefType "journal-article" @default.
- W2808932433 hasAuthorship W2808932433A5007188554 @default.
- W2808932433 hasAuthorship W2808932433A5014844829 @default.
- W2808932433 hasAuthorship W2808932433A5015017986 @default.
- W2808932433 hasAuthorship W2808932433A5035684336 @default.
- W2808932433 hasAuthorship W2808932433A5040508866 @default.
- W2808932433 hasAuthorship W2808932433A5060946821 @default.
- W2808932433 hasAuthorship W2808932433A5071221488 @default.
- W2808932433 hasConcept C127413603 @default.
- W2808932433 hasConcept C161790260 @default.
- W2808932433 hasConcept C171250308 @default.
- W2808932433 hasConcept C178790620 @default.
- W2808932433 hasConcept C185592680 @default.
- W2808932433 hasConcept C186187911 @default.
- W2808932433 hasConcept C192562407 @default.
- W2808932433 hasConcept C42360764 @default.
- W2808932433 hasConcept C82776694 @default.
- W2808932433 hasConceptScore W2808932433C127413603 @default.