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- W2809100967 abstract "We have prepared Eu2+ (1%) doped BaCl2 nanopowders by using a hybrid sol-gel/thermal decomposition route using barium acetate and trichloracetic acid as in situ chlorination agent. Structural and thermal analysis data have shown that orthorhombic BaCl2 phase crystallization occurs at 260 °C. BaCl2:Eu2+ nanocrystals of about 100–200 nm in size were produced after annealing (in air) at 500 °C and they displayed Eu2+ d → f type luminescence at 396 nm. X-ray photoelectron spectroscopy indicated the presence of both Eu2+, Eu3+ ions species and a BaO passivating layer at the surface of the nanocrystals. A polymer nanocomposite (PVP@BaCl2:Eu2+) was also processed and its optical response under x-ray irradiation was found to be similar to that of the nanopowder. X-ray excited luminescence showed Eu2+ luminescence at 396 nm, whereas the thermoluminescence peak at 130 °C was assigned to the F(Cl)-center recombination with Eu2+ related hole centers." @default.
- W2809100967 created "2018-06-29" @default.
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- W2809100967 date "2018-07-10" @default.
- W2809100967 modified "2023-09-27" @default.
- W2809100967 title "Investigation of sol-gel derived BaCl2:Eu2+ luminescent nanophosphor and the corresponding PVP@BaCl2:Eu2+ polymer nanocomposite" @default.
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- W2809100967 doi "https://doi.org/10.1088/1361-6463/aace7c" @default.
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