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- W2809165087 abstract "Abstract Reaction of the Rh(II) dimer [LRh]2(μ-Br)2 (L = ([2,6-Me2C6H3NCMe]2CH) with the bulky amide LiNH(2,6-iPr2C6H3) leads to a monomeric Rh(II) amide with a T-shape N3Rh arrangement and a pronounced agostic interaction. Reaction with the less bulky LiNH(2,6-Me2C6H3) results in benzylic C-H activation to a binuclear complex with a unique aza-xylylene bridging mode. With LiNHC6H5 we observe initial formation of [LRh]2(μ-NHPh)2 followed by N,C2′ coupling of two anilines. These reactions can be explained based on aminyl radical character of the Rh(II) amides (supported by EPR evidence) and/or involvement of nitrene intermediates." @default.
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- W2809165087 date "2018-10-01" @default.
- W2809165087 modified "2023-09-24" @default.
- W2809165087 title "Reactivity of Rhodium(II) amido/Rhodium(I) aminyl complexes" @default.
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- W2809165087 doi "https://doi.org/10.1016/j.ica.2018.06.015" @default.
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