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- W2809178676 abstract "Abstract A practical approach to the asymmetric synthesis of the ring A substructure of genkwadane A, a daphnane diterpenoid, was developed. This synthesis features the Mukaiyama aldol reaction to introduce the quaternary stereogenic center at C4 and VO(acac) 2 ‐catalyzed Jackson‐Ellman‐Bolm sulfoxidation to deliver the corresponding sulfoxide. The Dieckmann‐type condensation was efficiently promoted by KHMDS and the ring A substructure was finally accomplished through Barton iodination condition." @default.
- W2809178676 created "2018-06-29" @default.
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- W2809178676 date "2018-07-04" @default.
- W2809178676 modified "2023-09-26" @default.
- W2809178676 title "Asymmetric Synthesis of the Ring A Substructure of Genkwadane A" @default.
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- W2809178676 doi "https://doi.org/10.1002/cjoc.201800199" @default.
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