FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2809426304> ?p ?o ?g. }

• W2809426304 endingPage "598" @default.
• W2809426304 startingPage "588" @default.
• W2809426304 abstract "Hydrophobically modified ethoxylated urethane polymers (HEURs) are widely used to control the rheological profile of formulated particulate dispersions through associative network formation, the properties of which are perturbed by the presence of surfactants. At high polymer concentrations and in the presence of surfactants, it is hypothesised that the dominant factors in determining the rheological profile are the number and composition of the mixed hydrophobic aggregates, these being defined by the number and distribution of the hydrophobic linkers along the polymer backbone, rather than the end-group hydrophobe characteristics per se that dominate the low polymer concentration behaviour. Three different HEUR polymers with formulae (C6-L-(EO100-L)9-C6, C10-L-(EO200-L)4-C10 and C18-L-(EO200-L)7-C18 (where L = urethane linker, Cn = hydrophobic end-group chain length, and EO = ethylene oxide block) have been studied in the absence and presence of SDS employing techniques that quantify (a) the bulk characteristics of the polymer surfactant blend, (b) the structure and composition of the hydrophobic domains, (c) the dynamics of the polymer and surfactant, and (d) the polymer conformation. Collectively, these experiments demonstrate how molecular-level interactions between the HEURs and sodium dodecylsulfate (SDS) define the macroscopic behaviour of the polymer/surfactant mixture. Binding of the SDS to the polymer via two mechanisms – monomeric anti-cooperative and micellar cooperative – leads to surfactant-concentration-specific macroscopic changes in the viscosity. Binding of the surfactant to the polymer drives a conformational rearrangement, and an associated redistribution of the polymer end-groups and linker associations throughout the hydrophobic domains. The composition and size of these domains are sensitive to the polymer architecture. Therefore, there is a complex balance between polymer molecular weight, ethylene oxide block size, and number of urethane linkers, coupled with the size of the hydrophobic end-groups. In particular, the urethane linkers are shown to play a hitherto largely neglected but important role in driving the polymer association." @default.
• W2809426304 created "2018-06-29" @default.
• W2809426304 creator A5014281942 @default.
• W2809426304 creator A5025871957 @default.
• W2809426304 creator A5036270040 @default.
• W2809426304 creator A5046787976 @default.
• W2809426304 creator A5068509962 @default.
• W2809426304 creator A5082031200 @default.
• W2809426304 creator A5085098429 @default.
• W2809426304 date "2018-11-01" @default.
• W2809426304 modified "2023-09-23" @default.
• W2809426304 title "Studying the interaction of hydrophobically modified ethoxylated urethane (HEUR) polymers with sodium dodecylsulfate (SDS) in concentrated polymer solutions" @default.
• W2809426304 cites W1968760885 @default.
• W2809426304 cites W1972342051 @default.
• W2809426304 cites W1975881578 @default.
• W2809426304 cites W1981785477 @default.
• W2809426304 cites W1983975638 @default.
• W2809426304 cites W1989385992 @default.
• W2809426304 cites W1998472666 @default.
• W2809426304 cites W2011183648 @default.
• W2809426304 cites W2014753184 @default.
• W2809426304 cites W2016863295 @default.
• W2809426304 cites W2017979159 @default.
• W2809426304 cites W2019165999 @default.
• W2809426304 cites W2023234020 @default.
• W2809426304 cites W2024129712 @default.
• W2809426304 cites W2027781769 @default.
• W2809426304 cites W2028063689 @default.
• W2809426304 cites W2033718961 @default.
• W2809426304 cites W2049865865 @default.
• W2809426304 cites W2050163971 @default.
• W2809426304 cites W2056818925 @default.
• W2809426304 cites W2063866388 @default.
• W2809426304 cites W2065003425 @default.
• W2809426304 cites W2075363645 @default.
• W2809426304 cites W2088627063 @default.
• W2809426304 cites W2088796927 @default.
• W2809426304 cites W2108305553 @default.
• W2809426304 cites W2160809897 @default.
• W2809426304 cites W2333522168 @default.
• W2809426304 doi "https://doi.org/10.1016/j.jcis.2018.06.042" @default.
• W2809426304 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30031286" @default.
• W2809426304 hasPublicationYear "2018" @default.
• W2809426304 type Work @default.
• W2809426304 sameAs 2809426304 @default.
• W2809426304 citedByCount "5" @default.
• W2809426304 countsByYear W28094263042019 @default.
• W2809426304 countsByYear W28094263042020 @default.
• W2809426304 crossrefType "journal-article" @default.
• W2809426304 hasAuthorship W2809426304A5014281942 @default.
• W2809426304 hasAuthorship W2809426304A5025871957 @default.
• W2809426304 hasAuthorship W2809426304A5036270040 @default.
• W2809426304 hasAuthorship W2809426304A5046787976 @default.
• W2809426304 hasAuthorship W2809426304A5068509962 @default.
• W2809426304 hasAuthorship W2809426304A5082031200 @default.
• W2809426304 hasAuthorship W2809426304A5085098429 @default.
• W2809426304 hasBestOaLocation W28094263042 @default.
• W2809426304 hasConcept C11268172 @default.
• W2809426304 hasConcept C120001659 @default.
• W2809426304 hasConcept C127413603 @default.
• W2809426304 hasConcept C15920480 @default.
• W2809426304 hasConcept C159985019 @default.
• W2809426304 hasConcept C166940927 @default.
• W2809426304 hasConcept C178790620 @default.
• W2809426304 hasConcept C184651966 @default.
• W2809426304 hasConcept C185592680 @default.
• W2809426304 hasConcept C188027245 @default.
• W2809426304 hasConcept C192562407 @default.
• W2809426304 hasConcept C200990466 @default.
• W2809426304 hasConcept C2777801237 @default.
• W2809426304 hasConcept C42360764 @default.
• W2809426304 hasConcept C521977710 @default.
• W2809426304 hasConcept C55493867 @default.
• W2809426304 hasConcept C58226133 @default.
• W2809426304 hasConceptScore W2809426304C11268172 @default.
• W2809426304 hasConceptScore W2809426304C120001659 @default.
• W2809426304 hasConceptScore W2809426304C127413603 @default.
• W2809426304 hasConceptScore W2809426304C15920480 @default.
• W2809426304 hasConceptScore W2809426304C159985019 @default.
• W2809426304 hasConceptScore W2809426304C166940927 @default.
• W2809426304 hasConceptScore W2809426304C178790620 @default.
• W2809426304 hasConceptScore W2809426304C184651966 @default.
• W2809426304 hasConceptScore W2809426304C185592680 @default.
• W2809426304 hasConceptScore W2809426304C188027245 @default.
• W2809426304 hasConceptScore W2809426304C192562407 @default.
• W2809426304 hasConceptScore W2809426304C200990466 @default.
• W2809426304 hasConceptScore W2809426304C2777801237 @default.
• W2809426304 hasConceptScore W2809426304C42360764 @default.
• W2809426304 hasConceptScore W2809426304C521977710 @default.
• W2809426304 hasConceptScore W2809426304C55493867 @default.
• W2809426304 hasConceptScore W2809426304C58226133 @default.
• W2809426304 hasLocation W28094263041 @default.
• W2809426304 hasLocation W28094263042 @default.
• W2809426304 hasLocation W28094263043 @default.
• W2809426304 hasOpenAccess W2809426304 @default.
• W2809426304 hasPrimaryLocation W28094263041 @default.
• W2809426304 hasRelatedWork W1533289191 @default.
• W2809426304 hasRelatedWork W1964319407 @default.

• next