Matches in SemOpenAlex for { <https://semopenalex.org/work/W2809534465> ?p ?o ?g. }
- W2809534465 endingPage "1107" @default.
- W2809534465 startingPage "1098" @default.
- W2809534465 abstract "Electronic interactions between the cationic N,N'-bis(2(trimethylammonium iodide) ethylene)perylene-3,4,9,10-tetracarboxyldiimide (TAIPDI) with two electron donors, namely, pyrene (Py) and 1-pyrenesulfo-nic acid sodium salt (PySA), have been investigated. The spectroscopic studies showed the formation of the supramolecular conjugate between TAIPDI and PySA via ionic interaction, but not with Py. Density functional theory (DFT) combined with a natural energy decomposition analysis (NEDA) technique showed an S-like structure of the supramolecular conjugate TAIPDI-PySA via an ionic interaction. The formation constant of the TAIPDI-PySA supramolecular conjugate was determined to be 3.0 x 104 M−1, suggesting a fairly stable complex formation. The excited state events were monitored by both steady state and time-resolved emission techniques. Upon excitation, the quenching pathways via the singlet-excited states of TAIPDI and PySA involved the intramolecular electron transfer from the electron donating PySA to the electron accepting TAIPDI with a rate constant of 1.10 x 1011 s−1 and a quantum yield of 0.99. The thermodynamic parameters of the supramolecular TAIPDI-PySA conjugate have been determined using the stopped-flow technique." @default.
- W2809534465 created "2018-06-29" @default.
- W2809534465 creator A5007952802 @default.
- W2809534465 creator A5018818841 @default.
- W2809534465 creator A5063100925 @default.
- W2809534465 creator A5064037442 @default.
- W2809534465 date "2018-08-01" @default.
- W2809534465 modified "2023-09-27" @default.
- W2809534465 title "Intramolecular electron transfer of light harvesting perylene-pyrene supramolecular conjugate" @default.
- W2809534465 cites W1859334739 @default.
- W2809534465 cites W1963497199 @default.
- W2809534465 cites W1964295781 @default.
- W2809534465 cites W1964395868 @default.
- W2809534465 cites W1966013891 @default.
- W2809534465 cites W1971807067 @default.
- W2809534465 cites W1975234046 @default.
- W2809534465 cites W1982688671 @default.
- W2809534465 cites W1983649348 @default.
- W2809534465 cites W1994003821 @default.
- W2809534465 cites W1997022228 @default.
- W2809534465 cites W2002901794 @default.
- W2809534465 cites W2006857498 @default.
- W2809534465 cites W2012065239 @default.
- W2809534465 cites W2016425983 @default.
- W2809534465 cites W2018094686 @default.
- W2809534465 cites W2019796385 @default.
- W2809534465 cites W2022654083 @default.
- W2809534465 cites W2030820076 @default.
- W2809534465 cites W2032237080 @default.
- W2809534465 cites W2033196894 @default.
- W2809534465 cites W2036291730 @default.
- W2809534465 cites W2046230999 @default.
- W2809534465 cites W2048486567 @default.
- W2809534465 cites W2050081248 @default.
- W2809534465 cites W2051240069 @default.
- W2809534465 cites W2052567354 @default.
- W2809534465 cites W2052752040 @default.
- W2809534465 cites W2057938994 @default.
- W2809534465 cites W2060724006 @default.
- W2809534465 cites W2065497508 @default.
- W2809534465 cites W2069113196 @default.
- W2809534465 cites W2069169361 @default.
- W2809534465 cites W2069506896 @default.
- W2809534465 cites W2070227590 @default.
- W2809534465 cites W2082481686 @default.
- W2809534465 cites W2090988802 @default.
- W2809534465 cites W2092500291 @default.
- W2809534465 cites W2113005044 @default.
- W2809534465 cites W2114291309 @default.
- W2809534465 cites W2130664855 @default.
- W2809534465 cites W2142154858 @default.
- W2809534465 cites W2164257432 @default.
- W2809534465 cites W2170549062 @default.
- W2809534465 cites W2172213080 @default.
- W2809534465 cites W2326360929 @default.
- W2809534465 cites W2333040374 @default.
- W2809534465 cites W2416975419 @default.
- W2809534465 cites W2589415241 @default.
- W2809534465 cites W2593389916 @default.
- W2809534465 cites W2601081490 @default.
- W2809534465 cites W2627076588 @default.
- W2809534465 cites W2772646277 @default.
- W2809534465 cites W4237391075 @default.
- W2809534465 cites W4239186989 @default.
- W2809534465 cites W4251854412 @default.
- W2809534465 doi "https://doi.org/10.1039/c8pp00134k" @default.
- W2809534465 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29993078" @default.
- W2809534465 hasPublicationYear "2018" @default.
- W2809534465 type Work @default.
- W2809534465 sameAs 2809534465 @default.
- W2809534465 citedByCount "3" @default.
- W2809534465 countsByYear W28095344652021 @default.
- W2809534465 countsByYear W28095344652022 @default.
- W2809534465 countsByYear W28095344652023 @default.
- W2809534465 crossrefType "journal-article" @default.
- W2809534465 hasAuthorship W2809534465A5007952802 @default.
- W2809534465 hasAuthorship W2809534465A5018818841 @default.
- W2809534465 hasAuthorship W2809534465A5063100925 @default.
- W2809534465 hasAuthorship W2809534465A5064037442 @default.
- W2809534465 hasBestOaLocation W28095344651 @default.
- W2809534465 hasConcept C115624301 @default.
- W2809534465 hasConcept C121332964 @default.
- W2809534465 hasConcept C121745418 @default.
- W2809534465 hasConcept C123669783 @default.
- W2809534465 hasConcept C134306372 @default.
- W2809534465 hasConcept C145148216 @default.
- W2809534465 hasConcept C147597530 @default.
- W2809534465 hasConcept C152365726 @default.
- W2809534465 hasConcept C178790620 @default.
- W2809534465 hasConcept C181500209 @default.
- W2809534465 hasConcept C183882617 @default.
- W2809534465 hasConcept C185544564 @default.
- W2809534465 hasConcept C185592680 @default.
- W2809534465 hasConcept C188027245 @default.
- W2809534465 hasConcept C197336794 @default.
- W2809534465 hasConcept C2182769 @default.
- W2809534465 hasConcept C2778951431 @default.
- W2809534465 hasConcept C2779189646 @default.