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- W2809629954 abstract "The development of a highly efficient and low cost production process is instrumental for the wide application of VO2 and V2O3. In this paper, VO2 and V2O3 powders are successfully prepared via carbothermal reduction of V2O5 in a flowing Ar atmosphere at 973 K and 1423 K, respectively. Compared with the traditional methods, graphite is used as a reductant, which resulted in a low cost. The experimental results show that a high temperature assists in improving the kinetic rate. The phase transformation during the low-temperature reduction process between 948 K and 973 K occurs in the following sequential order: V2O5→V6O13→VO2. When the temperature is 1423 K or 1473 K, the phase transformation can be described as follows: V2O5→V3O5→V2O3. Owing to the shrink of the volume, the as-prepared VO2 and V2O3 particles could not maintain the original micro-morphology of V2O5. Relative to VO2, the as-prepared V2O3 particles are porous. It is also concluded that the V2O3 can be easily oxidized to VO2, when the partial pressure of O2 is in the range of 10−8 atm to 10−1 atm. Therefore, a reasonable reaction temperature and reaction time are important to prepare high purity V2O3." @default.
- W2809629954 created "2018-06-29" @default.
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- W2809629954 date "2018-09-01" @default.
- W2809629954 modified "2023-10-18" @default.
- W2809629954 title "A facile pathway to prepare VO2 and V2O3 powders via a carbothermal reduction process" @default.
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- W2809629954 doi "https://doi.org/10.1016/j.jssc.2018.06.016" @default.
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