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• W2809827303 abstract "Abstract Beryllate structures are marginally investigated, but show intriguing structural relations to oxo‐ and nitridosilicates. A typical feature is the coordination of Be in both trigonal planar and tetrahedral coordination by O. A broad range of structures is accessible by variable combinations of both building units. Three novel ternary Sr‐oxoberyllates are characterized by single‐crystal X‐ray diffraction analysis, density functional theory calculations and investigations on luminescence properties: α‐SrBeO 2 , β‐SrBeO 2 and Sr 12 Be 17 O 29 are obtained with oxoberyllate substructures, made up of either BeO 3 triangles or BeO 4 tetrahedra. The compounds can be described as chain‐ and layer‐type beryllates. When excited with blue light of (In,Ga)N LED chips, β‐SrBeO 2 and Sr 12 Be 17 O 29 show visible emission in the yellow and orange spectral range, respectively, upon doping with Eu 2+ . Exceptional narrow‐band yellow emission ( λ em =564 nm, fwhm=55 nm) makes β‐SrBeO 2 :Eu 2+ a promising phosphor for application in phosphor‐converted (pc‐)LEDs." @default.
• W2809827303 created "2018-07-10" @default.
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• W2809827303 date "2018-07-24" @default.
• W2809827303 modified "2023-09-26" @default.
• W2809827303 title "Oxoberyllates SrBeO₂ and Sr₁₂ Be₁₇ O₂₉ as Novel Host Materials for Eu²⁺ Luminescence" @default.
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• W2809827303 doi "https://doi.org/10.1002/chem.201801951" @default.
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• W2809827303 hasPublicationYear "2018" @default.
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