Matches in SemOpenAlex for { <https://semopenalex.org/work/W2809980509> ?p ?o ?g. }
- W2809980509 endingPage "11324" @default.
- W2809980509 startingPage "11321" @default.
- W2809980509 abstract "Tribenzotriquinacene (TBTQ) is a bowl-shaped molecule that has been widely used as a molecular building block in supramolecular and materials chemistry. Especially C3 -symmetric threefold-substituted TBTQs are interesting for these purposes. Until now a general and selective synthetic approach to those C3 -symmetric products was lacking, mainly because the typically used electrophilic aromatic substitution reactions of the parent TBTQ hydrocarbons produce predominantly the C1 isomer over the C3 isomer (3:1 statistical ratio). Herein we introduce a threefold borylation of TBTQ with the C3 isomer as the main product (2.6:1 C3 /C1 ratio). The borylated TBTQ can be converted in good yields into other C3 -symmetric TBTQs, thus allowing straightforward synthetic access to new building blocks for supramolecular and materials chemistry." @default.
- W2809980509 created "2018-07-10" @default.
- W2809980509 creator A5014261909 @default.
- W2809980509 creator A5043398784 @default.
- W2809980509 creator A5084670164 @default.
- W2809980509 date "2018-07-26" @default.
- W2809980509 modified "2023-10-18" @default.
- W2809980509 title "Switching the Statistical <i>C</i> <sub>3</sub> /<i>C</i> <sub>1</sub> Ratio in the Threefold Aromatic Substitution of Tribenzotriquinacenes towards the <i>C</i> <sub>3</sub> Isomer" @default.
- W2809980509 cites W1757134315 @default.
- W2809980509 cites W1967435272 @default.
- W2809980509 cites W1970817648 @default.
- W2809980509 cites W1974001124 @default.
- W2809980509 cites W1978708665 @default.
- W2809980509 cites W1984963453 @default.
- W2809980509 cites W1988055460 @default.
- W2809980509 cites W1992043705 @default.
- W2809980509 cites W2001635022 @default.
- W2809980509 cites W2004768063 @default.
- W2809980509 cites W2016252973 @default.
- W2809980509 cites W2018823964 @default.
- W2809980509 cites W2020714599 @default.
- W2809980509 cites W2025804869 @default.
- W2809980509 cites W2026260835 @default.
- W2809980509 cites W2047192281 @default.
- W2809980509 cites W2058505567 @default.
- W2809980509 cites W2062076168 @default.
- W2809980509 cites W2087155016 @default.
- W2809980509 cites W2106864170 @default.
- W2809980509 cites W2126703823 @default.
- W2809980509 cites W2130352972 @default.
- W2809980509 cites W2134581346 @default.
- W2809980509 cites W2138228581 @default.
- W2809980509 cites W2140132903 @default.
- W2809980509 cites W2144964649 @default.
- W2809980509 cites W2154020497 @default.
- W2809980509 cites W2158640749 @default.
- W2809980509 cites W2166958526 @default.
- W2809980509 cites W2168308494 @default.
- W2809980509 cites W2291597218 @default.
- W2809980509 cites W2327994729 @default.
- W2809980509 cites W2333841311 @default.
- W2809980509 cites W2473367233 @default.
- W2809980509 cites W2477649805 @default.
- W2809980509 cites W2480568375 @default.
- W2809980509 cites W2491242255 @default.
- W2809980509 cites W2508494712 @default.
- W2809980509 cites W2553149679 @default.
- W2809980509 cites W2560415354 @default.
- W2809980509 cites W2563395883 @default.
- W2809980509 cites W2775771329 @default.
- W2809980509 cites W2791324493 @default.
- W2809980509 cites W2949676065 @default.
- W2809980509 cites W4211041959 @default.
- W2809980509 cites W4231227339 @default.
- W2809980509 cites W4243735398 @default.
- W2809980509 doi "https://doi.org/10.1002/anie.201806332" @default.
- W2809980509 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29938890" @default.
- W2809980509 hasPublicationYear "2018" @default.
- W2809980509 type Work @default.
- W2809980509 sameAs 2809980509 @default.
- W2809980509 citedByCount "22" @default.
- W2809980509 countsByYear W28099805092018 @default.
- W2809980509 countsByYear W28099805092019 @default.
- W2809980509 countsByYear W28099805092020 @default.
- W2809980509 countsByYear W28099805092021 @default.
- W2809980509 countsByYear W28099805092022 @default.
- W2809980509 countsByYear W28099805092023 @default.
- W2809980509 crossrefType "journal-article" @default.
- W2809980509 hasAuthorship W2809980509A5014261909 @default.
- W2809980509 hasAuthorship W2809980509A5043398784 @default.
- W2809980509 hasAuthorship W2809980509A5084670164 @default.
- W2809980509 hasConcept C114614502 @default.
- W2809980509 hasConcept C147597530 @default.
- W2809980509 hasConcept C161790260 @default.
- W2809980509 hasConcept C178790620 @default.
- W2809980509 hasConcept C185592680 @default.
- W2809980509 hasConcept C199360897 @default.
- W2809980509 hasConcept C21951064 @default.
- W2809980509 hasConcept C2776413204 @default.
- W2809980509 hasConcept C2777210771 @default.
- W2809980509 hasConcept C2777965246 @default.
- W2809980509 hasConcept C2778220771 @default.
- W2809980509 hasConcept C2780263894 @default.
- W2809980509 hasConcept C2781076698 @default.
- W2809980509 hasConcept C32909587 @default.
- W2809980509 hasConcept C33923547 @default.
- W2809980509 hasConcept C41008148 @default.
- W2809980509 hasConcept C50027330 @default.
- W2809980509 hasConcept C71240020 @default.
- W2809980509 hasConcept C93275456 @default.
- W2809980509 hasConceptScore W2809980509C114614502 @default.
- W2809980509 hasConceptScore W2809980509C147597530 @default.
- W2809980509 hasConceptScore W2809980509C161790260 @default.
- W2809980509 hasConceptScore W2809980509C178790620 @default.
- W2809980509 hasConceptScore W2809980509C185592680 @default.
- W2809980509 hasConceptScore W2809980509C199360897 @default.
- W2809980509 hasConceptScore W2809980509C21951064 @default.
- W2809980509 hasConceptScore W2809980509C2776413204 @default.