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- W2810151209 abstract "An upper-rim functionalized calix[4]arene-based thiourea installed onto the (R,R)-1,2-cyclohexanediamine scaffold was synthesized with a view to investigate its catalytic ability in enantioselective Michael additions. The reactions were found to conveniently proceed under solvent-free conditions, observing good to high enantioselectivities. From this preliminary study, the calix[4]arene unit is likely to play a role in affecting the conversion and to a lesser extent to the stereochemical outcome of the reactions through van der Waals contacts and C–H···π interactions with the substrates." @default.
- W2810151209 created "2018-07-10" @default.
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- W2810151209 date "2018-07-01" @default.
- W2810151209 modified "2023-09-26" @default.
- W2810151209 title "Solvent-Free Enantioselective Michael Reactions Catalyzed by a Calixarene-Based Primary Amine Thiourea" @default.
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- W2810151209 doi "https://doi.org/10.1021/acs.joc.8b01454" @default.
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