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• W2810183748 abstract "Abstract In this work, ZnCo2S4 nanospheres in a hollow core-shell structure are synthesized by a facile self-template route. The synthesis route involves a solvothermal method synthesis of Zn-Co precursor solid spheres in glycerol and isopropanol and then sulfidation to obtain hollow ZnCo2S4 core-shell nanospheres. The synthesized obtain hollow ZnCo2S4 core-shell nanospheres possess mesoporous texture and its specific surface area is as large as 117.3 m2 g−1. Benefiting from the remarkable advantages such as novel hollow core-shell structures, mesoporous and large specific surface area, these ZnCo2S4 as electrode material exhibit a specific capacitance of 1045.3 F g−1 at 2.0 A g−1 and superior long-term cycling performance (around 4.5% loss after 5000 continuous cycling). Moreover, an asymmetric supercapacitor assembled with hollow ZnCo2S4 core-shell nanospheres and activated carbon delivers the energy density of 51.7 Wh kg−1 at a power density of 1700 W kg−1. Even at 6800 W kg−1, the energy density can still reach 42.5 Wh kg−1. This work not only demonstrates hollow ZnCo2S4 core-shell nanospheres utilized as a promising candidate for supercapacitors, but also provides a simple and cost-effective strategy for designing and synthesizing other high performance hollow structured metal-sulfides for electrochemical energy storage." @default.
• W2810183748 created "2018-07-10" @default.
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• W2810183748 date "2018-10-01" @default.
• W2810183748 modified "2023-09-29" @default.
• W2810183748 title "Mesoporous hollow ZnCo2S4 core-shell nanospheres for high performance supercapacitors" @default.
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• W2810183748 doi "https://doi.org/10.1016/j.ceramint.2018.06.215" @default.
• W2810183748 hasPublicationYear "2018" @default.
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