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- W2810359907 endingPage "8666" @default.
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- W2810359907 abstract "A ruthenium(II) complex bearing a naphthyridine-functionalized pyrazole ligand catalyzes oxidant-free and acceptorless selective double dehydrogenation of primary amines to nitriles at moderate temperature. The role of the proton-responsive entity on the ligand scaffold is demonstrated by control experiments, including the use of a N-methylated pyrazole analogue. DFT calculations reveal intricate hydride and proton transfers to achieve the overall elimination of 2 equiv of H2." @default.
- W2810359907 created "2018-07-10" @default.
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- W2810359907 date "2018-06-29" @default.
- W2810359907 modified "2023-10-12" @default.
- W2810359907 title "Double Dehydrogenation of Primary Amines to Nitriles by a Ruthenium Complex Featuring Pyrazole Functionality" @default.
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- W2810359907 doi "https://doi.org/10.1021/jacs.8b05009" @default.
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