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- W2810406944 abstract "Abstract A novel 2D zinc-based metal–organic framework [Zn(H2O)2(2,6-NDC)(NDI-A)]·2H2O (NDI-A = naphthalene carbodiimide-based acceptor, 2,6-NDC2− = 2, 6-naphthalenedicarboxylic group) (1) has been synthesized successfully, which shows excellent thermal stability that has been supported by thermogravimetric analysis (TGA). What's more, compound 1 exhibits photochromic and photo-controlled fluorescence quenching behaviors upon irradiation by 300 W xenon lamp accompanied by the formation of NDI-A radicals originating from electron transfer process. Interestingly, the electron transfer is based on both N H⋯O hydrogen bond and π-π stacking interactions, which is rare for NDI-type photochromic MOFs. The theory has been demonstrated by UV–vis absorption characterization analysis, electron paramagnetic resonance spectroscopy (ESR) and fluorescent spectroscopy." @default.
- W2810406944 created "2018-07-10" @default.
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- W2810406944 date "2018-08-01" @default.
- W2810406944 modified "2023-09-24" @default.
- W2810406944 title "A 2D photochromic zinc-based metal–organic framework with naphthalene diimide-type chromophore" @default.
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- W2810406944 doi "https://doi.org/10.1016/j.inoche.2018.06.018" @default.
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