FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2810408051> ?p ?o ?g. }

• W2810408051 endingPage "241" @default.
• W2810408051 startingPage "241" @default.
• W2810408051 abstract "Cap-rock integrity is an important consideration for geological storage of CO2. While CO2 bearing fluids are known to have reactivity to certain rock forming minerals, impurities including acid gases such as SOx, NOx, H2S or O2 may be present in injected industrial CO2 streams at varying concentrations, and may induce higher reactivity to cap-rock than pure CO2. Dissolution or precipitation of minerals may modify the porosity or permeability of cap-rocks and compromise or improve the seal. A calcite cemented cap-rock drill core sample (Evergreen Formation, Surat Basin) was experimentally reacted with formation water and CO2 containing SO2 and O2 at 60 °C and 120 bar. Solution pH was quickly buffered by dissolution of calcite cement, with dissolved ions including Ca, Mn, Mg, Sr, Ba, Fe and Si released to solution. Dissolved concentrations of several elements including Ca, Ba, Si and S had a decreasing trend after 200 h. Extensive calcite cement dissolution with growth of gypsum in the formed pore space, and barite precipitation on mineral surfaces were observed after reaction via SEM-EDS. A silica and aluminium rich precipitate was also observed coating grains. Kinetic geochemical modelling of the experimental data predicted mainly calcite and chlorite dissolution, with gypsum, kaolinite, goethite, smectite and barite precipitation and a slight net increase in mineral volume (decrease in porosity). To better approximate the experimental water chemistry it required the reactive surface areas of: (1) calcite cement decreased to 1 cm2/g; and, (2) chlorite increased to 7000 cm2/g. Models were then up-scaled and run for 30 or 100 years to compare the reactivity of calcite cemented, mudstone, siderite cemented or shale cap-rock sections of the Evergreen Formation in the Surat Basin, Queensland, Australia, a proposed target for future large scale CO2 storage. Calcite, siderite, chlorite and plagioclase were the main minerals dissolving. Smectite, siderite, ankerite, hematite and kaolinite were predicted to precipitate, with SO2 sequestered as anhydrite, alunite, and pyrite. Predicted net changes in porosity after reaction with CO2, CO2-SO2 or CO2-SO2-O2 were however minimal, which is favourable for cap-rock integrity. Mineral trapping of CO2 as siderite and ankerite however was only predicted in the CO2 or CO2-SO2 simulations. This indicates a limit on the injected O2 content may be needed to optimise mineral trapping of CO2, the most secure form of CO2 storage. Smectites were predicted to form in all simulations, they have relatively high CO2 sorption capacities and provide additional storage." @default.
• W2810408051 created "2018-07-10" @default.
• W2810408051 creator A5001477466 @default.
• W2810408051 creator A5002349411 @default.
• W2810408051 date "2018-06-29" @default.
• W2810408051 modified "2023-09-24" @default.
• W2810408051 title "Experimental Determination of Impure CO2 Alteration of Calcite Cemented Cap-Rock, and Long Term Predictions of Cap-Rock Reactivity" @default.
• W2810408051 cites W1021248308 @default.
• W2810408051 cites W1510038797 @default.
• W2810408051 cites W1968265566 @default.
• W2810408051 cites W1970999300 @default.
• W2810408051 cites W1977912344 @default.
• W2810408051 cites W1981214837 @default.
• W2810408051 cites W1983155242 @default.
• W2810408051 cites W1995838883 @default.
• W2810408051 cites W1998730244 @default.
• W2810408051 cites W2001586232 @default.
• W2810408051 cites W2003648515 @default.
• W2810408051 cites W2007478378 @default.
• W2810408051 cites W2012212083 @default.
• W2810408051 cites W2017833723 @default.
• W2810408051 cites W2019350506 @default.
• W2810408051 cites W2019811557 @default.
• W2810408051 cites W2022767769 @default.
• W2810408051 cites W2033838144 @default.
• W2810408051 cites W2041044410 @default.
• W2810408051 cites W2045020781 @default.
• W2810408051 cites W2054882070 @default.
• W2810408051 cites W2062229561 @default.
• W2810408051 cites W2063847231 @default.
• W2810408051 cites W2064572976 @default.
• W2810408051 cites W2065759708 @default.
• W2810408051 cites W2067268593 @default.
• W2810408051 cites W2069250865 @default.
• W2810408051 cites W2076857865 @default.
• W2810408051 cites W2081423026 @default.
• W2810408051 cites W2113888807 @default.
• W2810408051 cites W2127530599 @default.
• W2810408051 cites W2127887153 @default.
• W2810408051 cites W2154492036 @default.
• W2810408051 cites W2247702125 @default.
• W2810408051 cites W2323332857 @default.
• W2810408051 cites W2334629173 @default.
• W2810408051 cites W2576924630 @default.
• W2810408051 cites W2737407816 @default.
• W2810408051 cites W2740619812 @default.
• W2810408051 cites W2748496236 @default.
• W2810408051 cites W2748880838 @default.
• W2810408051 cites W2751698922 @default.
• W2810408051 cites W2756978600 @default.
• W2810408051 cites W2763435801 @default.
• W2810408051 cites W2768521166 @default.
• W2810408051 cites W4236978110 @default.
• W2810408051 cites W562042183 @default.
• W2810408051 doi "https://doi.org/10.3390/geosciences8070241" @default.
• W2810408051 hasPublicationYear "2018" @default.
• W2810408051 type Work @default.
• W2810408051 sameAs 2810408051 @default.
• W2810408051 citedByCount "11" @default.
• W2810408051 countsByYear W28104080512019 @default.
• W2810408051 countsByYear W28104080512020 @default.
• W2810408051 countsByYear W28104080512021 @default.
• W2810408051 countsByYear W28104080512022 @default.
• W2810408051 crossrefType "journal-article" @default.
• W2810408051 hasAuthorship W2810408051A5001477466 @default.
• W2810408051 hasAuthorship W2810408051A5002349411 @default.
• W2810408051 hasBestOaLocation W28104080511 @default.
• W2810408051 hasConcept C127313418 @default.
• W2810408051 hasConcept C147789679 @default.
• W2810408051 hasConcept C151730666 @default.
• W2810408051 hasConcept C185592680 @default.
• W2810408051 hasConcept C191897082 @default.
• W2810408051 hasConcept C192562407 @default.
• W2810408051 hasConcept C199289684 @default.
• W2810408051 hasConcept C2776044767 @default.
• W2810408051 hasConcept C2777844515 @default.
• W2810408051 hasConcept C2779229104 @default.
• W2810408051 hasConcept C2779870107 @default.
• W2810408051 hasConcept C2780191791 @default.
• W2810408051 hasConcept C523993062 @default.
• W2810408051 hasConcept C88380143 @default.
• W2810408051 hasConcept C94556721 @default.
• W2810408051 hasConceptScore W2810408051C127313418 @default.
• W2810408051 hasConceptScore W2810408051C147789679 @default.
• W2810408051 hasConceptScore W2810408051C151730666 @default.
• W2810408051 hasConceptScore W2810408051C185592680 @default.
• W2810408051 hasConceptScore W2810408051C191897082 @default.
• W2810408051 hasConceptScore W2810408051C192562407 @default.
• W2810408051 hasConceptScore W2810408051C199289684 @default.
• W2810408051 hasConceptScore W2810408051C2776044767 @default.
• W2810408051 hasConceptScore W2810408051C2777844515 @default.
• W2810408051 hasConceptScore W2810408051C2779229104 @default.
• W2810408051 hasConceptScore W2810408051C2779870107 @default.
• W2810408051 hasConceptScore W2810408051C2780191791 @default.
• W2810408051 hasConceptScore W2810408051C523993062 @default.
• W2810408051 hasConceptScore W2810408051C88380143 @default.
• W2810408051 hasConceptScore W2810408051C94556721 @default.
• W2810408051 hasFunder F4320320984 @default.

• next