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- W2810772023 abstract "The first structural and compositional details of a low-stage graphite interaction compound (GIC) containing Mg are reported, with the GIC obtained by combining magnesium metal and graphite powder in ethylenediamine (en) at 100 °C under an inert atmosphere. Thermal analyses indicate the bottle-green stage 1 product has a composition of [Mg(en)1.0]C13. X-ray diffraction shows a c-axis expansion of 0.55 nm, indicating the presence of intercalate monolayers with the en cointercalate oriented perpendicular to the encasing graphene layers. Redox titration indicates two electrons are transferred per Mg. A structural model is proposed with dimeric [Mg2(en)2]2+ intercalate species." @default.
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- W2810772023 date "2018-06-25" @default.
- W2810772023 modified "2023-09-25" @default.
- W2810772023 title "Graphite Intercalation by Mg Diamine Complexes" @default.
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- W2810772023 doi "https://doi.org/10.1021/acs.inorgchem.8b01250" @default.
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