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- W2810795280 abstract "We have reimagined the traditional physical chemistry sequence to emphasize connections between topics. In this chapter, we focus on a key set of linking topics in physical chemistry: partition functions and statistical thermodynamics. We cover the Boltzmann distribution in the first course, then return to discuss partition functions at the beginning of the second course. We then work with statistical thermodynamics throughout the rest of the second course. Through a set of spreadsheet exercises in the second course, students gain facility with partition functions and statistical thermodynamics and how they interface with both quantum mechanics and classical thermodynamics. Starting from spectroscopic data, students calculate partition functions, thermal energies, entropies, temperature independent energies of reaction, and ultimately free energies of reaction in order to calculate thermodynamic quantities for observed reactions and predict whether or not a speculative reaction will occur. In this way, students keep using statistical thermodynamics while further aspects of quantum mechanics, classical thermodynamics, and kinetics are covered in class and in the laboratory. Student performance and response to the spreadsheet exercises are discussed, followed by possible implications for other physical chemistry faculty members." @default.
- W2810795280 created "2018-07-10" @default.
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- W2810795280 date "2018-01-01" @default.
- W2810795280 modified "2023-10-18" @default.
- W2810795280 title "Partition Functions and Statistical Thermodynamics: Spreadsheet Activities To Promote Connections in Physical Chemistry" @default.
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- W2810795280 doi "https://doi.org/10.1021/bk-2018-1279.ch004" @default.
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