Matches in SemOpenAlex for { <https://semopenalex.org/work/W2810911744> ?p ?o ?g. }
- W2810911744 endingPage "12030" @default.
- W2810911744 startingPage "12022" @default.
- W2810911744 abstract "Abstract Investigations of solid mixtures of the elemental combinations A/Tl/Pb (A=Na, K) and K/Tl/Bi indicate the presence of multiple binary and ternary Zintl phases, among them new ones containing Tl and Pb or Bi, respectively. Extractions with en/crypt‐222 afford single crystals of several novel binary anions, including [Tl@Tl 4 Pb 8 ] 4− and (Tl 4 Bi 3 ) 3− . [Tl@Tl 4 Pb 8 ] 4− adopts a closo ‐type cage structure despite possessing one additional electron; it is therefore isostructural, yet not isoelectronic, with homoatomic [Tl@Tl 12 ] 11− obtained by solid state reactions. (Tl 4 Bi 3 ) 3− is a rare case of a pentagonal bipyramidal Zintl anion, yet the first binary one, and (unlike Tl 7 7− ) the first one with a proper closo ‐type electron count. Assignment of the numbers and positions of the Tl/Pb or Tl/Bi atoms within the anionic clusters, indistinguishable in classical X‐ray diffraction experiments, was achieved by means of quantum chemistry. The studies shed light on the complex situation in solid heavy element mixtures and their substantial differences from the composition of the Zintl anions obtained from them by extraction." @default.
- W2810911744 created "2018-07-10" @default.
- W2810911744 creator A5020738851 @default.
- W2810911744 creator A5037933314 @default.
- W2810911744 creator A5045921773 @default.
- W2810911744 creator A5076273697 @default.
- W2810911744 creator A5079304905 @default.
- W2810911744 date "2018-07-23" @default.
- W2810911744 modified "2023-09-25" @default.
- W2810911744 title "The Identity of “Ternary” A/Tl/Pb or K/Tl/Bi Solid Mixtures and Binary Zintl Anions Isolated From Their Solutions" @default.
- W2810911744 cites W1474177264 @default.
- W2810911744 cites W1628591393 @default.
- W2810911744 cites W188801585 @default.
- W2810911744 cites W1965206452 @default.
- W2810911744 cites W1965890865 @default.
- W2810911744 cites W1966140209 @default.
- W2810911744 cites W1967099587 @default.
- W2810911744 cites W1969246928 @default.
- W2810911744 cites W1969509776 @default.
- W2810911744 cites W1974623450 @default.
- W2810911744 cites W1977899647 @default.
- W2810911744 cites W1980718745 @default.
- W2810911744 cites W1981373638 @default.
- W2810911744 cites W1982717807 @default.
- W2810911744 cites W1982718477 @default.
- W2810911744 cites W1988376578 @default.
- W2810911744 cites W1992085502 @default.
- W2810911744 cites W1992428710 @default.
- W2810911744 cites W1993671107 @default.
- W2810911744 cites W2012668533 @default.
- W2810911744 cites W2015553247 @default.
- W2810911744 cites W2019907317 @default.
- W2810911744 cites W2019917612 @default.
- W2810911744 cites W2021481762 @default.
- W2810911744 cites W2025856127 @default.
- W2810911744 cites W2032719166 @default.
- W2810911744 cites W2033912140 @default.
- W2810911744 cites W2034714947 @default.
- W2810911744 cites W2038288666 @default.
- W2810911744 cites W2038568105 @default.
- W2810911744 cites W2043671443 @default.
- W2810911744 cites W2048999452 @default.
- W2810911744 cites W2049013599 @default.
- W2810911744 cites W2049048912 @default.
- W2810911744 cites W2050259998 @default.
- W2810911744 cites W2055400493 @default.
- W2810911744 cites W2055563809 @default.
- W2810911744 cites W2064221444 @default.
- W2810911744 cites W2067650379 @default.
- W2810911744 cites W2068808464 @default.
- W2810911744 cites W2069545642 @default.
- W2810911744 cites W2071342268 @default.
- W2810911744 cites W2071802677 @default.
- W2810911744 cites W2085345596 @default.
- W2810911744 cites W2086451979 @default.
- W2810911744 cites W2088965396 @default.
- W2810911744 cites W2092630919 @default.
- W2810911744 cites W2093076921 @default.
- W2810911744 cites W2097932887 @default.
- W2810911744 cites W2107841899 @default.
- W2810911744 cites W2112572092 @default.
- W2810911744 cites W2120500904 @default.
- W2810911744 cites W2126006562 @default.
- W2810911744 cites W2135025522 @default.
- W2810911744 cites W2137256935 @default.
- W2810911744 cites W2141850069 @default.
- W2810911744 cites W2141930165 @default.
- W2810911744 cites W2144717230 @default.
- W2810911744 cites W2146606147 @default.
- W2810911744 cites W2147044568 @default.
- W2810911744 cites W2150098183 @default.
- W2810911744 cites W2161361443 @default.
- W2810911744 cites W2162382924 @default.
- W2810911744 cites W2163015315 @default.
- W2810911744 cites W2169390022 @default.
- W2810911744 cites W2261542628 @default.
- W2810911744 cites W2270113252 @default.
- W2810911744 cites W2300440225 @default.
- W2810911744 cites W2316328113 @default.
- W2810911744 cites W2327898169 @default.
- W2810911744 cites W2329082285 @default.
- W2810911744 cites W2332766234 @default.
- W2810911744 cites W2334881518 @default.
- W2810911744 cites W2412229041 @default.
- W2810911744 cites W2466299476 @default.
- W2810911744 cites W2502372942 @default.
- W2810911744 cites W2517364786 @default.
- W2810911744 cites W2518263656 @default.
- W2810911744 cites W2557838702 @default.
- W2810911744 cites W2567364945 @default.
- W2810911744 cites W2732501976 @default.
- W2810911744 cites W2746554462 @default.
- W2810911744 cites W2754206731 @default.
- W2810911744 cites W2790697069 @default.
- W2810911744 cites W2949409596 @default.
- W2810911744 cites W2949895171 @default.
- W2810911744 cites W2950461121 @default.
- W2810911744 cites W2950867483 @default.