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- W2810975737 abstract "Novel bowl-like, apple-like, and spherical PdCu alloy hollow microparticles with mesoporous nanoshells are synthesized through a simple disproportionation reaction route using a spherical Cu2O template with increasing H2PdCl4 ratio. The diameter of hollow particles is about 1 μm, and the thickness of mesoporous shells is about 50 nm. The obtained bowl-like PdCu alloy hollow microparticles with mesoporous nanoshells exhibit the highest electrocatalytic activity among the apple-like and spherical PdCu hollow microparticles and commercial Pd/C electrocatalysts toward methanol anodic oxidation for fuel cells. The remarkably excellent electrocatalytic performance of bowl-like PdCu alloy electrocatalysts might be attributed to the unique bowl-like hollow architecture with highly mesoporous nanoshells which are constructed by self-supported PdCu nanoparticles. The strategy presented here might help pave the way for the synthesis of novel nano-/microcomplex hollow materials with mesoporous nanoshells." @default.
- W2810975737 created "2018-07-10" @default.
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- W2810975737 date "2018-06-25" @default.
- W2810975737 modified "2023-10-16" @default.
- W2810975737 title "Bowl-Like and Apple-Like PdCu Hollow Microparticles with Mesoporous Nanoshells: Synthesis, Characterization, and Electrocatalytic Performance" @default.
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- W2810975737 doi "https://doi.org/10.1021/acsaem.8b00523" @default.
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