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- W2811131805 abstract "Electrochemical reduction of CO2 to value-added chemicals by using renewable electricity offers a promising strategy to deal with rising CO2 emission and the energy crisis. Single-site zinc-coordinated nitrogen-codoped graphene (Zn-N-G) catalyzes the electrochemical reduction of CO2 to CO. The Zn-N-G catalyst exhibits excellent intrinsic activity toward CO2 reduction, reaching a faradaic efficiency of 91 % for CO production at a low overpotential of 0.39 V. X-ray absorption fine structure and X-ray photoelectron spectroscopy both confirm the presence of isolated Zn-Nx moieties, which act as the key active sites for CO formation. DFT calculations reveal the origin of enhanced activity for CO2 reduction on Zn-N-G catalysts. This work provide further understanding of the active centers on transition metal-nitrogen-carbon (M-N-C) catalysts for electrochemical reduction of CO2 to CO." @default.
- W2811131805 created "2018-07-10" @default.
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- W2811131805 creator A5072629781 @default.
- W2811131805 creator A5086702541 @default.
- W2811131805 date "2018-07-26" @default.
- W2811131805 modified "2023-10-06" @default.
- W2811131805 title "Zinc-Coordinated Nitrogen-Codoped Graphene as an Efficient Catalyst for Selective Electrochemical Reduction of CO<sub>2</sub> to CO" @default.
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- W2811131805 doi "https://doi.org/10.1002/cssc.201800925" @default.
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- W2811131805 hasPublicationYear "2018" @default.
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