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- W281214914 abstract "We have presented full details of our work on alkylboranes, which we have introduced as new reagents for copper-catalyzed SN2′-type enantioselective allylic substitutions. The copper catalysis delivered enantioenriched chiral products containing tertiary or quaternary carbon stereogenic centers branched with functionalized sp3-alkyl groups. The wide availability of alkylboranes via the established alkene hydroboration reaction is an attractive feature of these transformations. Various functional groups are tolerated in the substrates. A reaction pathway involving addition–elimination of a neutral alkylcopper(I) species with the allyl chloride substrate is proposed." @default.
- W281214914 created "2016-06-24" @default.
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- W281214914 date "2015-09-01" @default.
- W281214914 modified "2023-09-29" @default.
- W281214914 title "Copper-catalyzed enantioselective allylic cross-coupling with alkylboranes" @default.
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- W281214914 doi "https://doi.org/10.1016/j.tet.2015.05.048" @default.
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