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- W281236411 abstract "The rate-law, temperature and pressure dependences for the ligand exchange reaction of dimethylsulfide on Pd(Me2S2)2Cl2 were measured by 1H NMR in the solvents chloroform, dichloromethane, o-dichlorobenzene and benzonitrile. The respective experimental ΔH*, ΔS* and Δ* values are: 38.5 kJ mol−1, −69.7 J K−1 mol−1 and −7.1 cm3 mol−1:33.4 −85.6 and −8.4: 36.1, −70.2 and -7.2; 38.1, −67.4 and −5.4. the experimental ΔV* were correlated to the solvent electrostriction parameter qp leading to a values of −5.9 ± 1.6 cm3 mol−1 for ΔV*int, and a very small Δ*solv contribution. The activation parameters and the second order rate law lead to the assignment of a highly symmetrical associative ligand exchange pathway with a trigonal bipyramidal transition state or intermediate, without charge separation or important dipole formation during the activation process." @default.
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- W281236411 date "1983-01-01" @default.
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- W281236411 title "Variable-temperature and variable-pressure 1H NMR studies of dimethylsulfide exchange on trans-bis(dimethylsulfide)dichloropalladium(II) in various solvent [1]" @default.
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- W281236411 doi "https://doi.org/10.1016/s0020-1693(00)83652-x" @default.
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