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- W2814965812 abstract "Isonitriles have excellent electronic compatibility to react with free radicals. Recently, photoredox catalysis has emerged as a powerful tool for the construction of C–C bonds with few protocols for alkylative heterocycle synthesis through isonitrile addition. Herein, we describe the photocatalytic generation of alkyl radicals from unactivated bromoalkanes as part of an efficient cross-coupling strategy for the diversification of isonitriles using a dimeric gold(I) photoredox catalyst, [Au2(dppm)2]Cl2." @default.
- W2814965812 created "2018-07-19" @default.
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- W2814965812 date "2018-07-06" @default.
- W2814965812 modified "2023-10-10" @default.
- W2814965812 title "Transformations of Isonitriles with Bromoalkanes Using Photoredox Gold Catalysis" @default.
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- W2814965812 doi "https://doi.org/10.1021/acs.joc.8b01380" @default.
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