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- W2816405052 abstract "The gas-phase radiolysis of a mixture of toluene or ethylbenzene and dimethylamine has been studied at room temperature as a function of the dimethylamine pressure in order to investigate the structure and reactivity of the C7H7+ ion. The structure of the C7H7+ ion which takes part in the subsequent ion-molecule reaction was suggested to be the benzyl type on the basis of the reaction products. The radiolyses of toluene-α-d3 and ethylbenzene-α-d2 in the presence and in the absence of dimethylamine have been investigated, and the following information has been obtained: (i) the C7H7+ ion formed from toluene and ethylbenzene mainly consists of the benzyl ion, retaining its original structure; (ii) two types of scrambling processes may be involved in the C7H7+ ion formation, one of which, especially important in the case of toluene, includes the ring expansion of the original molecular ion, while the other consists of repeated rapid isomerization between the benzyl ion and the tropylium ion. These results we..." @default.
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- W2816405052 date "1974-06-01" @default.
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- W2816405052 title "The Structure and Reactivity of Organic Ions in Gas-phase Radiolysis. VIII. The C7H7+Ion from Toluene and Ethylbenzene" @default.
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- W2816405052 doi "https://doi.org/10.1246/bcsj.47.1387" @default.
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