Matches in SemOpenAlex for { <https://semopenalex.org/work/W2824562734> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W2824562734 endingPage "26575" @default.
- W2824562734 startingPage "26566" @default.
- W2824562734 abstract "Anchoring Rh complexes to the surface of a silica polyamine composite, which has a poly(allylamine) covalently grafted to the surface of amorphous silica gel, yielded a material that proved to be an effective and novel heterogeneous catalyst for hydroformylation of unsaturated compounds. Surface amino groups of the material were modified with phosphines by covalent and ionic coupling. The modified materials were then treated with Rh(acac)(CO)2, giving the catalysts K-1 and K-2. Catalysts were characterized by solid-state NMR spectroscopy, IR spectroscopy, XPS, TEM, and elemental analysis. The activity and stability of K-1 and K-2 were then studied for the hydroformylation of selected unsaturated compounds. Hydroformylation of terminal double bonds occurred selectively in the presence of internal double bonds. Characterization of the catalysts and the problems encountered with the supported catalysts are discussed. Catalyst K-1 is reusable and can be applied to the hydroformylation of linear olefins, styrene, 4-vinylcyclohexene, and dienes, as well as representative terpenes and other unsaturated hydrocarbons in a batch reactor." @default.
- W2824562734 created "2018-07-19" @default.
- W2824562734 creator A5009119371 @default.
- W2824562734 creator A5018565227 @default.
- W2824562734 creator A5022258357 @default.
- W2824562734 creator A5043856480 @default.
- W2824562734 creator A5089159962 @default.
- W2824562734 creator A5043182955 @default.
- W2824562734 date "2018-07-06" @default.
- W2824562734 modified "2023-10-12" @default.
- W2824562734 title "New Heterogeneous Rh-Containing Catalysts Immobilized on a Hybrid Organic–Inorganic Surface for Hydroformylation of Unsaturated Compounds" @default.
- W2824562734 cites W1972755567 @default.
- W2824562734 cites W1981349624 @default.
- W2824562734 cites W1981566786 @default.
- W2824562734 cites W1982500361 @default.
- W2824562734 cites W1991222564 @default.
- W2824562734 cites W1998212968 @default.
- W2824562734 cites W2006792934 @default.
- W2824562734 cites W2008666215 @default.
- W2824562734 cites W2008728979 @default.
- W2824562734 cites W2025037011 @default.
- W2824562734 cites W2043029295 @default.
- W2824562734 cites W2052199929 @default.
- W2824562734 cites W2053843228 @default.
- W2824562734 cites W2056101070 @default.
- W2824562734 cites W2059416486 @default.
- W2824562734 cites W2103523022 @default.
- W2824562734 cites W2149940246 @default.
- W2824562734 cites W2163947690 @default.
- W2824562734 cites W2188726338 @default.
- W2824562734 cites W2257061395 @default.
- W2824562734 cites W2329518550 @default.
- W2824562734 cites W2411594478 @default.
- W2824562734 cites W4211046907 @default.
- W2824562734 cites W4248484987 @default.
- W2824562734 doi "https://doi.org/10.1021/acsami.8b02797" @default.
- W2824562734 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29979868" @default.
- W2824562734 hasPublicationYear "2018" @default.
- W2824562734 type Work @default.
- W2824562734 sameAs 2824562734 @default.
- W2824562734 citedByCount "31" @default.
- W2824562734 countsByYear W28245627342019 @default.
- W2824562734 countsByYear W28245627342020 @default.
- W2824562734 countsByYear W28245627342021 @default.
- W2824562734 countsByYear W28245627342022 @default.
- W2824562734 countsByYear W28245627342023 @default.
- W2824562734 crossrefType "journal-article" @default.
- W2824562734 hasAuthorship W2824562734A5009119371 @default.
- W2824562734 hasAuthorship W2824562734A5018565227 @default.
- W2824562734 hasAuthorship W2824562734A5022258357 @default.
- W2824562734 hasAuthorship W2824562734A5043182955 @default.
- W2824562734 hasAuthorship W2824562734A5043856480 @default.
- W2824562734 hasAuthorship W2824562734A5089159962 @default.
- W2824562734 hasConcept C100805817 @default.
- W2824562734 hasConcept C15920480 @default.
- W2824562734 hasConcept C161790260 @default.
- W2824562734 hasConcept C175583648 @default.
- W2824562734 hasConcept C178790620 @default.
- W2824562734 hasConcept C180577832 @default.
- W2824562734 hasConcept C185592680 @default.
- W2824562734 hasConcept C188027245 @default.
- W2824562734 hasConcept C192562407 @default.
- W2824562734 hasConcept C2777566558 @default.
- W2824562734 hasConcept C521398313 @default.
- W2824562734 hasConcept C521977710 @default.
- W2824562734 hasConceptScore W2824562734C100805817 @default.
- W2824562734 hasConceptScore W2824562734C15920480 @default.
- W2824562734 hasConceptScore W2824562734C161790260 @default.
- W2824562734 hasConceptScore W2824562734C175583648 @default.
- W2824562734 hasConceptScore W2824562734C178790620 @default.
- W2824562734 hasConceptScore W2824562734C180577832 @default.
- W2824562734 hasConceptScore W2824562734C185592680 @default.
- W2824562734 hasConceptScore W2824562734C188027245 @default.
- W2824562734 hasConceptScore W2824562734C192562407 @default.
- W2824562734 hasConceptScore W2824562734C2777566558 @default.
- W2824562734 hasConceptScore W2824562734C521398313 @default.
- W2824562734 hasConceptScore W2824562734C521977710 @default.
- W2824562734 hasFunder F4320321079 @default.
- W2824562734 hasIssue "31" @default.
- W2824562734 hasLocation W28245627341 @default.
- W2824562734 hasLocation W28245627342 @default.
- W2824562734 hasOpenAccess W2824562734 @default.
- W2824562734 hasPrimaryLocation W28245627341 @default.
- W2824562734 hasRelatedWork W2068085831 @default.
- W2824562734 hasRelatedWork W2070956392 @default.
- W2824562734 hasRelatedWork W2088143306 @default.
- W2824562734 hasRelatedWork W2170119575 @default.
- W2824562734 hasRelatedWork W2344683157 @default.
- W2824562734 hasRelatedWork W2951458411 @default.
- W2824562734 hasRelatedWork W2969992498 @default.
- W2824562734 hasRelatedWork W2977702061 @default.
- W2824562734 hasRelatedWork W3155947632 @default.
- W2824562734 hasRelatedWork W4211242886 @default.
- W2824562734 hasVolume "10" @default.
- W2824562734 isParatext "false" @default.
- W2824562734 isRetracted "false" @default.
- W2824562734 magId "2824562734" @default.
- W2824562734 workType "article" @default.