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- W282783006 abstract "The the rmal, catalyti c, and acid- catalyzed transformation of 3, 3,5-triphenylpyr az olenine4-carboxylic acid esters was studied. The thermal and acid-catalyzed isomerization of the pyrazolenines leads not only to pyrazoles but also to isopyrazotes. A mechanism involving a 1,5-suprafacial sigmatropic shift is proposed for the isomerization. It is shown that the migration of substituents from the 4 position of the pyrazolenine ring, which has been previously proposed as a variant of the van Alphen rearrangement, does not occur." @default.
- W282783006 created "2016-06-24" @default.
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- W282783006 date "1975-01-01" @default.
- W282783006 modified "2023-09-24" @default.
- W282783006 title "CATALYTIC, AND PHOTOLYTIC TRANSFORMATIO'N OF 3,3,5- TRIPHENYLPYRAZ OLENINE-4-CARBOX YLIC ACID ESTERS*" @default.
- W282783006 hasPublicationYear "1975" @default.
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