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- W2829019145 abstract "The possibility of the 3,4-dihydroxyphenyl groups introduction into polybutadiene-1,2 was studied with help of two methods (using cross-metathesis or thiol-ene reaction) in order to obtain new potential adhesive materials. Eugenol was used as a source of 3,4-dihydroxyphenyl groups, which was preliminary protected by (C2H5)3SiH in the presence of B(C6F5)3 as a catalyst. It was found that the cross-metathesis of polybutadiene-1,2 and the protected eugenol over different Grubbs catalysts preliminary resulted in a destruction of the polymer with a formation of low molecular weight products. At the same time based on thiol-ene click-reaction it was realized a simple and effective method for the synthesis of polymer materials containing 3,4-dihydroxyphenyl groups with desired molecular weights based on polybutadiene-1,2." @default.
- W2829019145 created "2018-07-19" @default.
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- W2829019145 date "2018-01-01" @default.
- W2829019145 modified "2023-09-23" @default.
- W2829019145 title "A new approach to the synthesis of polymers bearing 3,4-dihydroxyphenyl-moieties in side groups from eugenol and polybutadiene with help of thiol-ene reaction" @default.
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- W2829019145 doi "https://doi.org/10.1063/1.5046040" @default.
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