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• W2832377151 abstract "The design and preparation of transition-metal complexes with Schiff base ligands are of interest due to their potential applications in the fields of molecular magnetism, nonlinear optics, dye-sensitized solar cells (DSSCs), sensing and photoluminescence. Luminescent metal complexes have been suggested as potential phosphors in electroluminescent devices. A new luminescent nickel(II) complex, [Ni(C10H10Cl2NO2)2], has been synthesized and characterized by single-crystal X-ray diffraction and elemental analysis, UV-Vis, FT-IR, 1H NMR, 13C NMR and photoluminescence spectroscopies, and LC-MS/MS. Molecules of the complex in the crystals lie on special positions, on crystallographic binary rotation axes. The NiII atoms are six-coordinated by two phenolate O, two imine N and two hydroxy O atoms from two tridentate Schiff base 2,4-dichloro-6-[(2-hydroxypropyl)iminomethyl]phenolate ligands, forming an elongated octahedral geometry. Furthermore, the complex exhibits a strong green luminescence emission in the solid state at room temperature, as can be seen from the (CIE) chromaticity diagram, and hence the complex may be a promising green OLED (organic light-emitting diode) in the development of electroluminescent materials for flat-panel-display applications." @default.
• W2832377151 created "2018-07-19" @default.
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• W2832377151 date "2018-07-06" @default.
• W2832377151 modified "2023-09-27" @default.
• W2832377151 title "Structural and spectroscopic characterization of a new luminescent Ni^II complex: bis{2,4-dichloro-6-[(2-hydroxypropyl)iminomethyl]phenolato-κ³ <i>O</i>,<i>N</i>,<i>O</i>′}nickel(II)" @default.
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• W2832377151 doi "https://doi.org/10.1107/s2053229618009166" @default.
• W2832377151 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30080164" @default.
• W2832377151 hasPublicationYear "2018" @default.
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