Matches in SemOpenAlex for { <https://semopenalex.org/work/W2835418444> ?p ?o ?g. }
- W2835418444 endingPage "11687" @default.
- W2835418444 startingPage "11683" @default.
- W2835418444 abstract "Herein we report the isolation and characterization of aminal intermediates in the organocatalytic α-chlorination of aldehydes. These species are stable covalent ternary adducts of the substrate, the catalyst and the chlorinating reagent. NMR-assisted kinetic studies and isotopic labeling experiments with the isolated intermediate did not support its involvement in downstream stereoselective processes as proposed by Blackmond. By tuning the reactivity of the chlorinating reagent, we were able to suppress the accumulation of rate-limiting off-cycle intermediates. As a result, an efficient and highly enantioselective catalytic system with a broad functional group tolerance was developed." @default.
- W2835418444 created "2018-07-19" @default.
- W2835418444 creator A5004736187 @default.
- W2835418444 creator A5020691789 @default.
- W2835418444 creator A5021643459 @default.
- W2835418444 creator A5030002004 @default.
- W2835418444 creator A5033600382 @default.
- W2835418444 creator A5056407680 @default.
- W2835418444 creator A5060787706 @default.
- W2835418444 date "2018-08-03" @default.
- W2835418444 modified "2023-10-12" @default.
- W2835418444 title "Mechanistic Studies on the Organocatalytic α‐Chlorination of Aldehydes: The Role and Nature of Off‐Cycle Intermediates" @default.
- W2835418444 cites W1980544299 @default.
- W2835418444 cites W1982446660 @default.
- W2835418444 cites W1994533618 @default.
- W2835418444 cites W1997792770 @default.
- W2835418444 cites W2012123343 @default.
- W2835418444 cites W2024493923 @default.
- W2835418444 cites W2050346320 @default.
- W2835418444 cites W2054605505 @default.
- W2835418444 cites W2083016696 @default.
- W2835418444 cites W2095713785 @default.
- W2835418444 cites W2099714760 @default.
- W2835418444 cites W2104635036 @default.
- W2835418444 cites W2105191081 @default.
- W2835418444 cites W2131703825 @default.
- W2835418444 cites W2135804326 @default.
- W2835418444 cites W2153212528 @default.
- W2835418444 cites W2154926242 @default.
- W2835418444 cites W2165291048 @default.
- W2835418444 cites W2166796782 @default.
- W2835418444 cites W2264038220 @default.
- W2835418444 cites W2315413551 @default.
- W2835418444 cites W2320721360 @default.
- W2835418444 cites W2323080246 @default.
- W2835418444 cites W2343571601 @default.
- W2835418444 cites W2545770380 @default.
- W2835418444 cites W2609958867 @default.
- W2835418444 cites W2766151591 @default.
- W2835418444 cites W2949114673 @default.
- W2835418444 cites W4205216182 @default.
- W2835418444 cites W4233534311 @default.
- W2835418444 cites W4235299123 @default.
- W2835418444 cites W4246239099 @default.
- W2835418444 cites W4253060968 @default.
- W2835418444 doi "https://doi.org/10.1002/anie.201806261" @default.
- W2835418444 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29999220" @default.
- W2835418444 hasPublicationYear "2018" @default.
- W2835418444 type Work @default.
- W2835418444 sameAs 2835418444 @default.
- W2835418444 citedByCount "15" @default.
- W2835418444 countsByYear W28354184442020 @default.
- W2835418444 countsByYear W28354184442021 @default.
- W2835418444 countsByYear W28354184442022 @default.
- W2835418444 countsByYear W28354184442023 @default.
- W2835418444 crossrefType "journal-article" @default.
- W2835418444 hasAuthorship W2835418444A5004736187 @default.
- W2835418444 hasAuthorship W2835418444A5020691789 @default.
- W2835418444 hasAuthorship W2835418444A5021643459 @default.
- W2835418444 hasAuthorship W2835418444A5030002004 @default.
- W2835418444 hasAuthorship W2835418444A5033600382 @default.
- W2835418444 hasAuthorship W2835418444A5056407680 @default.
- W2835418444 hasAuthorship W2835418444A5060787706 @default.
- W2835418444 hasConcept C108204754 @default.
- W2835418444 hasConcept C111368507 @default.
- W2835418444 hasConcept C127313418 @default.
- W2835418444 hasConcept C142724271 @default.
- W2835418444 hasConcept C146686406 @default.
- W2835418444 hasConcept C161790260 @default.
- W2835418444 hasConcept C178790620 @default.
- W2835418444 hasConcept C180577832 @default.
- W2835418444 hasConcept C181199279 @default.
- W2835418444 hasConcept C185592680 @default.
- W2835418444 hasConcept C192937433 @default.
- W2835418444 hasConcept C204787440 @default.
- W2835418444 hasConcept C21951064 @default.
- W2835418444 hasConcept C2776910235 @default.
- W2835418444 hasConcept C2777289219 @default.
- W2835418444 hasConcept C40875361 @default.
- W2835418444 hasConcept C63338738 @default.
- W2835418444 hasConcept C66972969 @default.
- W2835418444 hasConcept C71924100 @default.
- W2835418444 hasConcept C86756495 @default.
- W2835418444 hasConceptScore W2835418444C108204754 @default.
- W2835418444 hasConceptScore W2835418444C111368507 @default.
- W2835418444 hasConceptScore W2835418444C127313418 @default.
- W2835418444 hasConceptScore W2835418444C142724271 @default.
- W2835418444 hasConceptScore W2835418444C146686406 @default.
- W2835418444 hasConceptScore W2835418444C161790260 @default.
- W2835418444 hasConceptScore W2835418444C178790620 @default.
- W2835418444 hasConceptScore W2835418444C180577832 @default.
- W2835418444 hasConceptScore W2835418444C181199279 @default.
- W2835418444 hasConceptScore W2835418444C185592680 @default.
- W2835418444 hasConceptScore W2835418444C192937433 @default.
- W2835418444 hasConceptScore W2835418444C204787440 @default.
- W2835418444 hasConceptScore W2835418444C21951064 @default.
- W2835418444 hasConceptScore W2835418444C2776910235 @default.
- W2835418444 hasConceptScore W2835418444C2777289219 @default.