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- W2838686258 abstract "Summary Mononuclear cyclopentadienylcobalt carbonyl and cyclopentadienyliron carbonyl derivatives were covalently linked to a silica gel support either by reaction of (C2HsO)Si(CH3hCsHs or of (C2H sOhSiCsH s with macroporous 'silica gel supported materials and subsequent treatment with Co2 (CO>S or Fe2 (CO)9 or by reaction of (C2HsO)Si(CH3)2CsH4Co(COh and (C2HsO)3SiCsH4Co(CO)2 with a silica gel support. In contrast to their unsupported analogues, no bi nuclear or polynuclear species are formed from the Si02-supported metal car bonyl derivatives even at temperatures up to 200°C. The cobalt derivative was found to be a catalyst for olefin hydroformylation reactions. Binuclear Si02-8upported species are formed when [{C2HsO)Si(CH3)2CsH4Fe (CO )21~ or [(C2HsO)3SiCsHcFe(CO)212 are treated with a silica gel support. A large fraction of these surface-bound dimers are irreversibly converted into mononuclear hydridoiron carbonyl derivatives by hydrogen at elevated pressures." @default.
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- W2838686258 date "1978-01-01" @default.
- W2838686258 modified "2023-09-27" @default.
- W2838686258 title "SlJPPORTED CYCLOPENTADIENYLMETAL CARBONYL COMPLEXES ill *. SILICA-GEL-SUPPORTED IRON AND COBALT DERIVATIVES" @default.
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