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- W283937557 abstract "In this work, SBA-15 was selected as a support for the homoleptic chelating N-heterocyclic carbene complexes of palladium. Here, Pd2+ ions were coordinated to N-heterocyclic carbene (NHC–Pd) which also contain ionic liquid. Then, this NHC–[email protected]/IL catalyst (NHC–Pd active part of the catalyst) was successfully applied in the catalysis of Hiyama coupling reaction with lower mol% Pd rather to previously reported literatures. The role of TBAF and Cs2CO3 in the decrease of Pd mol% was crucial. Recyclability test showed a successful reusability for 5 runs. Simultaneous application of TBAF and NaOH did destroy the silica structure of SBA-15 in the first run." @default.
- W283937557 created "2016-06-24" @default.
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- W283937557 date "2015-08-01" @default.
- W283937557 modified "2023-09-26" @default.
- W283937557 title "Homoleptic chelating N-heterocyclic carbene complexes of palladium immobilized within the pores of SBA-15/IL (NHC–Pd@SBA-15/IL) as heterogeneous catalyst for Hiyama reaction" @default.
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- W283937557 doi "https://doi.org/10.1016/j.jorganchem.2015.05.019" @default.
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