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- W28528075 abstract "Publisher Summary Under normal circumstances, a nickel-based superalloy is protected from corrosive attack by an oxide layer on the surface, which is Cr2O3. However, in marine environments, turbine blades made from superalloys are susceptible to corrosive attack by hot or molten salts. The chapter explores the range of conditions that might lead to the hot salt corrosion in an attempt to provide a basis for understanding the detailed mechanisms involved. The driving force for corrosion is thermodynamic and hence it is attractive to analyze corrosion by reference to thermodynamic criteria. Corrosion involves a series of processes that are linked together in a complex way. For the case of hot salt corrosion, the mechanism by which chromium is removed from the surface of the turbine blade is complex and might involve some sort of fluxing whereby the Cr2O3 is re-precipitated from the salt phase at its boundary with the gas phase. Traditionally, corrosion problems have been analyzed thermodynamically in terms of so-called phase stability diagrams. Such diagrams are conceptually simple but are limited to the systems where the material is a pure element. In the view of the progress made in calculating phase equilibria involving many components and a wide range of phases, it is appealing to analyze the corrosion phenomenon as a multi-component system." @default.
- W28528075 created "2016-06-24" @default.
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- W28528075 date "2008-01-01" @default.
- W28528075 modified "2023-09-23" @default.
- W28528075 title "Hot salt corrosion of superalloys" @default.
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- W28528075 doi "https://doi.org/10.1533/9781845693954.2.77" @default.
- W28528075 hasPublicationYear "2008" @default.
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