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• W2854290731 abstract "Abstract Six isomers of sodium para-dimethyl dodecylbenzene sulfonates ( p -S12) were synthesized by a series of reactions. The surface tension of the isomers p -S12 in an aqueous NaCl solution (4000 mg/L) was measured. From the data the following parameters were calculated: critical micelle concentration (CMC), the surface tension at the CMC ( γ CMC ), the surface excess concentration at surface saturation ( Γ max ) and the area per molecule at surface saturation ( A s min ). The A s min increased and the Γ max decreased when the aromatic nucleus moves to the center of long-chain alkyl group. The dynamic interfacial tensions (DIFT) between p -S12 in 4000 mg/L NaCl aqueous solution and five n -paraffins were measured by using a spinning drop technique. The DIFT of the p -S12 showed the characteristic that the interfacial tension (IFT) is low at the beginning, then increases, reaches a maximum value, and finally continues to decrease until it reaches a stable value. By the measurement of alkane carbon number for the minimum IFT, n min , of the six isomers solutions, we found that the n min firstly decreases and then increases when the aromatic nucleus moves to the long-chain alkyl group. This phenomenon is due to the differences of hydrophilic-lipophilic properties and the structure of the p -S12 isomers." @default.
• W2854290731 created "2018-07-19" @default.
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• W2854290731 date "2018-07-11" @default.
• W2854290731 modified "2023-09-26" @default.
• W2854290731 title "Synthesis and Interfacial Tensions of Sodium <i>p</i>-Dimethyl Dodecylbenzene Sulfonates" @default.
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• W2854290731 doi "https://doi.org/10.3139/113.110569" @default.
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