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- W285688182 abstract "Raman spectroscopy is now so highly dependent on excitation by laser light sources that it hardly seems possible that C.V. Raman could have first observed this faint scattering phenomenon using filtered sunlight [1–4]. First predicted in 1923 by Adolf Smekel [5], the Raman effect is the scattering of an incident photon shifted in frequency by an allowed vibrational frequency of the scattering molecule. Thus, the Raman spectrum, like the infrared spectrum, yields information about the vibrational frequencies of molecules. Unlike infrared absorption, which results from an interaction of the incident radiation with the electric dipole of the molecule, Raman scattering results from an interaction of this radiation with the polarizability tensor [6]. The practical result is that the Raman spectrum does not yield exactly the same vibrational information as does the infrared spectrum, since the selection rules are different. A second result is that the Raman effect results in a very weak scattering spectrum. In classical Raman spectroscopy, only about one photon in 108 which reaches a sample is scattered (hence the need for sources with high spectral brightness). In spite of this severe limitation, investigations of the Raman effect and its use in chemical spectroscopy proceeded relatively rapidly even prior to the availability of laser sources, and hundreds, if not thousands, of papers on Raman spectroscopy had been published by the end of the 1950’s. After the laser replaced the Toronto arc as the standard light source [7] an even wider range of investigations became possible." @default.
- W285688182 created "2016-06-24" @default.
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- W285688182 date "1987-01-01" @default.
- W285688182 modified "2023-09-25" @default.
- W285688182 title "Raman Spectroscopy of Biomolecules" @default.
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- W285688182 doi "https://doi.org/10.1007/978-3-540-47872-0_21" @default.
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