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• W2859744260 abstract "A strategic methodology has been developed to effectively synthesize the fac-[Re(CO)3(dcbH2)(trans-stpy)]+ complex, where dcbH2 = 2,2′-bipyridine-4,4′-dicarboxylic acid and trans-stpy = trans-4-styrylpyridine, which has been designed to efficiently absorb visible light. The complex exhibits outstanding trans-to-cis photoisomerization with 436 nm irradiation (Φtrans→cis = 0.50 ± 0.03), in contrast to the photochemical behavior previously reported in the literature (Faustino, L. A.; et al. Inorg. Chem. 2018, 57, 2933–2941). The main emphasis here is to address the synthetic strategy for obtaining the actual complex, its characterization, and an accurate description of its photochemical and photophysical behavior, which reveal new insights into this complex." @default.
• W2859744260 created "2018-07-19" @default.
• W2859744260 creator A5016699812 @default.
• W2859744260 creator A5046509841 @default.
• W2859744260 creator A5081399162 @default.
• W2859744260 date "2018-07-11" @default.
• W2859744260 modified "2023-10-12" @default.
• W2859744260 title "Visible Photosensitization of <i>trans</i>-Styrylpyridine Coordinated to <i>fac</i>-[Re(CO)₃(dcbH₂)]⁺: New Insights" @default.
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• W2859744260 doi "https://doi.org/10.1021/acs.inorgchem.8b01304" @default.
• W2859744260 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29992817" @default.
• W2859744260 hasPublicationYear "2018" @default.
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