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- W2867359216 abstract "Abstract We report on the development of a supramolecular nanocarrier concept that allows for the encapsulation and separation of small apolar molecules from water. The nanocarriers consist of shell‐by‐shell‐coated nanoparticles such as TiO 2 and ferromagnetic Fe 3 O 4 . The first ligand shell is provided by covalently bound hexadecyl phosphonic acid (PAC 16 ) and the second shell by noncovalently assembled amphiphiles rendering the hybrid architecture soluble in water. Agitation of these constructs with water containing the hydrocarbons G1 – G4 , the fluorescent marker G5 , the polychlorinated biphenyl PCB 77, or crude oil leads to a very efficient uptake (up to 411 %) of the apolar contaminant. In case of the hybrids containing a Fe 3 O 4 core, straightforward phase separation by the action of an external magnet is provided. The load can easily be released by a final treatment with an organic solvent." @default.
- W2867359216 created "2018-07-19" @default.
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- W2867359216 date "2018-08-17" @default.
- W2867359216 modified "2023-10-18" @default.
- W2867359216 title "Highly Efficient Encapsulation and Phase Separation of Apolar Molecules by Magnetic Shell‐by‐Shell‐Coated Nanocarriers in Water" @default.
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- W2867359216 doi "https://doi.org/10.1002/chem.201802419" @default.
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