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- W287890507 abstract "The magnetic moments and the absorption and reflection spectra of octahedral titanium (III) complexes [Ti(III)A6] [where A = H2O, NH3 or CO(NH2)2] are discussed fiom the point of view of the ligand field theory. The experimental results are in agreement with the Jahn-Teller theorem. The magnetic and spectroscopic findings indicate a ligand field component of lower symmetry (tetragonal or rhombic). In the case of Cs Ti(III)(SO4)2·12H2O the static crystal field is of trigonal symmetry with respect to crystallographic investigations on alums. A field of D3-symmetry is not able to remove the twofold orbital degeneracy of the 2Eg-excited state of the octahedron. The existence of two bands (Δν ~ 2000 cm-1) is in this case probably the result of a dynamical Jahn-Teller effect." @default.
- W287890507 created "2016-06-24" @default.
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- W287890507 date "1964-01-01" @default.
- W287890507 modified "2023-09-24" @default.
- W287890507 title "LICHTABSORPTIONSEIGENSCHAFTEN UND MAGNETISCHE MOMENTE VON OKTAEDRISCHEN KOMPLEXVERBINDUNGEN DES III-WERTIGEN TITANS" @default.
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- W287890507 doi "https://doi.org/10.1016/b978-1-4832-2841-9.50018-0" @default.
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