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- W2879259319 abstract "The synthesis and structural characterization of metalloid gold clusters stabilized by sulfur ligands has increased massively in the last decade. The metalloid gold clusters are synthesized via a reduction of a gold precursor and most metalloid gold clusters are stabilized via aryl thiolate ligands. It is also possible to use thiosilyl or phosphine groups as stabilizing ligands. Here, we present a small Au 6 cluster as a possible intermediate of the formation of large metalloid clusters, together with the synthesis of a variety of defined Au I precursors that contain a phosphine or a phosphite group as well as a thiosilyl ligand, which can be further used for the synthesis of metalloid gold clusters." @default.
- W2879259319 created "2018-07-19" @default.
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- W2879259319 date "2018-08-26" @default.
- W2879259319 modified "2023-09-30" @default.
- W2879259319 title "Synthesis and Characterization of Gold Silyl Compounds with Different Phosphine or Phosphite Groups for Reduction Reactions" @default.
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- W2879259319 doi "https://doi.org/10.1002/ejic.201800595" @default.
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