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• W2882052495 abstract "Langmuir monolayers consisting of fatty acid molecules were prepared on solutions of FeCl3 and LaCl3 to investigate adsorption of trivalent metal ions on carboxylic headgroups by using sum-frequency vibrational spectroscopy. Fe3+ ions bound to the fatty acid headgroups only in the form of hydroxide complexes (Fe(OH)x+3-x), and sum-frequency intensity of water stretch modes increased markedly upon adsorption of ion hydroxide. On the other hand, La3+ ions bound to the charged anionic headgroup as bare trivalent ions. Upon Fe(OH)x+3-x adsorption, the sum-frequency spectrum of carboxyl headgroups showed significant redshift which is opposite to the case of La3+ as well as those for alkali (Na+, K+) and alkali earth metal (Ca2+, Mg2+) ions, which also supports that Fe3+ binding is by covalent metal-ligand bonding, while La3+ binding is by Coulomb attraction." @default.
• W2882052495 created "2018-07-19" @default.
• W2882052495 creator A5002551670 @default.
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• W2882052495 date "2018-07-09" @default.
• W2882052495 modified "2023-10-14" @default.
• W2882052495 title "Binding of trivalent ions on fatty acid Langmuir monolayer: Fe3+ versus La3+" @default.
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• W2882052495 doi "https://doi.org/10.1063/1.5028296" @default.
• W2882052495 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30384741" @default.
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