Matches in SemOpenAlex for { <https://semopenalex.org/work/W2883176021> ?p ?o ?g. }
- W2883176021 endingPage "2490" @default.
- W2883176021 startingPage "2481" @default.
- W2883176021 abstract "Generating monovalent pnictogens within NCN pincers has resulted in the isolation of three distinct types of 1,2-azaheteroles, highly aromatic nitrogen analogues like pyrazole-based 5, aromatic yet fluxional P- and As-derived bell-clappers 1 and 2, and hypervalent Sb and Bi derivatives 3 and 4, which are supported by 3-center, 4-electron N–E–N bonds. Careful analysis of the solid-state structures of 1–5/[5-Me][OTf] in combination with NICS calculations (at the GIAO/M06/cc-pVTZ(-PP) level) and other computational methods (NBO) suggest that simpler NC chelates may support new phosphorus- and arsenic-containing heterocycles. Indeed, reduction of ECl2 (E = P or As) derivatives supported by N-Dipp (Dipp = 2,6-diisopropylphenyl) substituted NC bidentate ligands produced 1,2-benzoazaphosphole 11 and 1,2-benzoazaarsole 12. NICS calculations revealed 11 and 12 had aromatic character on par with that of pyrazole-based 5." @default.
- W2883176021 created "2018-08-03" @default.
- W2883176021 creator A5000957727 @default.
- W2883176021 creator A5030442304 @default.
- W2883176021 creator A5043688549 @default.
- W2883176021 creator A5057664957 @default.
- W2883176021 creator A5057803757 @default.
- W2883176021 creator A5062987999 @default.
- W2883176021 creator A5066141952 @default.
- W2883176021 creator A5076191791 @default.
- W2883176021 creator A5076620253 @default.
- W2883176021 date "2018-07-16" @default.
- W2883176021 modified "2023-10-06" @default.
- W2883176021 title "Heterocycles Derived from Generating Monovalent Pnictogens within NCN Pincers and Bidentate NC Chelates: Hypervalency versus Bell-Clappers versus Static Aromatics" @default.
- W2883176021 cites W1436326676 @default.
- W2883176021 cites W1929861762 @default.
- W2883176021 cites W1963740321 @default.
- W2883176021 cites W1965850303 @default.
- W2883176021 cites W1966191734 @default.
- W2883176021 cites W1968438795 @default.
- W2883176021 cites W1969657397 @default.
- W2883176021 cites W1970500083 @default.
- W2883176021 cites W1971515240 @default.
- W2883176021 cites W1971944586 @default.
- W2883176021 cites W1978484184 @default.
- W2883176021 cites W1982077483 @default.
- W2883176021 cites W1991646450 @default.
- W2883176021 cites W1991980693 @default.
- W2883176021 cites W1999879040 @default.
- W2883176021 cites W2000815209 @default.
- W2883176021 cites W2000828198 @default.
- W2883176021 cites W2005148229 @default.
- W2883176021 cites W2006846423 @default.
- W2883176021 cites W2007378462 @default.
- W2883176021 cites W2009330894 @default.
- W2883176021 cites W2012933943 @default.
- W2883176021 cites W2013272088 @default.
- W2883176021 cites W2014975207 @default.
- W2883176021 cites W2020270681 @default.
- W2883176021 cites W2022222509 @default.
- W2883176021 cites W2022394799 @default.
- W2883176021 cites W2024113894 @default.
- W2883176021 cites W2027454290 @default.
- W2883176021 cites W2037481719 @default.
- W2883176021 cites W2037982748 @default.
- W2883176021 cites W2039062198 @default.
- W2883176021 cites W2039713929 @default.
- W2883176021 cites W2042944554 @default.
- W2883176021 cites W2048997806 @default.
- W2883176021 cites W2053248916 @default.
- W2883176021 cites W2054021060 @default.
- W2883176021 cites W2054729462 @default.
- W2883176021 cites W2056248674 @default.
- W2883176021 cites W2057263316 @default.
- W2883176021 cites W2057460345 @default.
- W2883176021 cites W2059131038 @default.
- W2883176021 cites W2063851575 @default.
- W2883176021 cites W2066641436 @default.
- W2883176021 cites W2069361460 @default.
- W2883176021 cites W2070678541 @default.
- W2883176021 cites W2076144502 @default.
- W2883176021 cites W2080435995 @default.
- W2883176021 cites W2082146998 @default.
- W2883176021 cites W2085540176 @default.
- W2883176021 cites W2109948016 @default.
- W2883176021 cites W2110898183 @default.
- W2883176021 cites W2116493292 @default.
- W2883176021 cites W2125122393 @default.
- W2883176021 cites W2133065742 @default.
- W2883176021 cites W2133242809 @default.
- W2883176021 cites W2137765175 @default.
- W2883176021 cites W2145355644 @default.
- W2883176021 cites W2153019670 @default.
- W2883176021 cites W2157969816 @default.
- W2883176021 cites W2171088777 @default.
- W2883176021 cites W2173315031 @default.
- W2883176021 cites W2316444823 @default.
- W2883176021 cites W2319341839 @default.
- W2883176021 cites W2319930012 @default.
- W2883176021 cites W2320281272 @default.
- W2883176021 cites W2324513581 @default.
- W2883176021 cites W2332390614 @default.
- W2883176021 cites W2412116119 @default.
- W2883176021 cites W2419130748 @default.
- W2883176021 cites W2469611741 @default.
- W2883176021 cites W2504697089 @default.
- W2883176021 cites W2522091374 @default.
- W2883176021 cites W2562926786 @default.
- W2883176021 cites W2589441793 @default.
- W2883176021 cites W2605567134 @default.
- W2883176021 cites W2611776526 @default.
- W2883176021 cites W2621446385 @default.
- W2883176021 cites W2727078233 @default.
- W2883176021 cites W2751612273 @default.
- W2883176021 cites W2949723284 @default.
- W2883176021 cites W2949900542 @default.
- W2883176021 cites W2949924050 @default.
- W2883176021 cites W2950007144 @default.